Superlattice induced by electron-beam irradiation in magnetic ferroelectric BiMnO3
文献类型:期刊论文
作者 | Chi, ZH ; Yang, H ; Li, FY ; Yu, RC ; Jin, CQ ; Wang, XH ; Deng, XY ; Li, LT |
刊名 | JOURNAL OF PHYSICS-CONDENSED MATTER
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出版日期 | 2006 |
卷号 | 18期号:17页码:4371 |
关键词 | TEMPERATURE POLYMORPHISM METASTABLE BIMNO3 |
ISSN号 | 0953-8984 |
通讯作者 | Jin, CQ (reprint author), Chinese Acad Sci, Beijing Natl Lab Condensed Matter Phys, POB 603, Beijing 100080, Peoples R China. |
中文摘要 | Single-phased polycrystalline BiMnO3 (hereinafter abbreviated as BMO) ceramic was fabricated via high-pressure solid-state reaction. Microstructure modification of selective grains, signalled by emergence of superlattice diffraction, was scrutinized by means of electron diffraction (ED) combined with high-resolution transmission electron microscopy (HRTEM). It was clearly evidenced that the well established C2 monoclinic substructure (a = 9.53 angstrom, b = 5.61 angstrom, c = 9.85 angstrom and beta = 110.67 degrees) of BMO (Atou et al 1999 J. Solid State Chem. 145 639) is metastable and prone to be transformed to a new pseudocubic superstructure (a approximate to b approximate to c approximate to 15.8 angstrom and a alpha approximate to beta approximate to gamma approximate to 90 degrees) (Yang et al 2006 Phys. Rev. B 73 024114) when irradiated continuously by an electron beam. Magnetization measurement unveiled a unique ferromagnetic phase transition at 103 K, which corroborated our speculation that as-prepared BMO ceramic is free of polymorphism at ambient conditions. |
收录类别 | SCI |
语种 | 英语 |
公开日期 | 2013-09-24 |
源URL | [http://ir.iphy.ac.cn/handle/311004/54118] ![]() |
专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
推荐引用方式 GB/T 7714 | Chi, ZH,Yang, H,Li, FY,et al. Superlattice induced by electron-beam irradiation in magnetic ferroelectric BiMnO3[J]. JOURNAL OF PHYSICS-CONDENSED MATTER,2006,18(17):4371. |
APA | Chi, ZH.,Yang, H.,Li, FY.,Yu, RC.,Jin, CQ.,...&Li, LT.(2006).Superlattice induced by electron-beam irradiation in magnetic ferroelectric BiMnO3.JOURNAL OF PHYSICS-CONDENSED MATTER,18(17),4371. |
MLA | Chi, ZH,et al."Superlattice induced by electron-beam irradiation in magnetic ferroelectric BiMnO3".JOURNAL OF PHYSICS-CONDENSED MATTER 18.17(2006):4371. |
入库方式: OAI收割
来源:物理研究所
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