Surface compatibility in a carbon-alloy composite and its influence on the electrochemical performance of Lihon batteries
文献类型：期刊论文
| 作者 | Wu, XD ; Wang, ZX ; Chen, LQ ; Huang, XJ |
| 刊名 | CARBON
 |
| 出版日期 | 2004 |
| 卷号 | 42期号:10页码:1965 |
| 关键词 | LITHIUM-ION-BATTERIES RECHARGEABLE BATTERIES ANODE MATERIAL HARD CARBON INSERTION TEMPERATURE SPHERULES ELECTRODE |
| ISSN号 | 0008-6223 |
| 通讯作者 | Chen, LQ (reprint author), Chinese Acad Sci, Inst Phys, Lab Solid State Ion, POB 603, Beijing 100080, Peoples R China. |
| 中文摘要 | Carbon-alloy composites were prepared by coating carbon materials with different surfaces with Sn, Sb or SnSb. The SnSb-hard carbon spherule (HCS) composite electrode shows the best cycling performance. The matching of crystalline parameters between SnSb and the carbon ensures a good dispersion of SnSb alloy on the surface. The high density of the nucleation centers on the HCS surface leads to a small SnSb crystallite size. Open pores on the surface of HCS, into which the alloy crystals are allowed to grow, act as pinning centers, which further stabilize the composite. These three factors are supposed to be responsible for the best cyclic performance of SnSb-HCS composite. The latter two factors also result in a large BET surface area, which leads to a large initial irreversible capacity loss, because more solid electrolyte interface film is formed. It seems that the best cyclic performance and the highest initial efficiency are paradoxical in the SnSb-carbon composite. Further surface modification should be conducted to obtain better electrode materials. (C) 2004 Elsevier Ltd. All rights reserved. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2013-09-24 |
| 源URL | [http://ir.iphy.ac.cn/handle/311004/54156]  |
| 专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
| 推荐引用方式 GB/T 7714 | Wu, XD,Wang, ZX,Chen, LQ,et al. Surface compatibility in a carbon-alloy composite and its influence on the electrochemical performance of Lihon batteries[J]. CARBON,2004,42(10):1965. |
| APA | Wu, XD,Wang, ZX,Chen, LQ,&Huang, XJ.(2004).Surface compatibility in a carbon-alloy composite and its influence on the electrochemical performance of Lihon batteries.CARBON,42(10),1965. |
| MLA | Wu, XD,et al."Surface compatibility in a carbon-alloy composite and its influence on the electrochemical performance of Lihon batteries".CARBON 42.10(2004):1965. |
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来源：物理研究所
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