Surface-enhanced Raman scattering study on passivating films of Ag electrodes in lithium batteries
文献类型:期刊论文
作者 | Li, H ; Mo, YJ ; Pei, N ; Xu, XX ; Huang, XJ ; Chen, LQ |
刊名 | JOURNAL OF PHYSICAL CHEMISTRY B
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出版日期 | 2000 |
卷号 | 104期号:35页码:8477 |
关键词 | PROPYLENE CARBONATE SOLUTIONS TRANSFORM INFRARED-SPECTROSCOPY NOBLE-METAL ELECTRODES IN-SITU RAMAN SILVER SURFACES GRAPHITE INTERCALATION ELECTROLYTES ANODES CHEMISTRY |
ISSN号 | 1089-5647 |
通讯作者 | Mo, YJ (reprint author), Henan Univ, Dept Phys, Kaifeng 475001, Peoples R China. |
中文摘要 | Li/Ag and Li/Al electrochemical cells composed of smooth Ag or Al electrode sheets, respectively, and matched with nonaqueous electrolytes were assembled and discharged. Discharged Ag electrodes were investigated using micro-Raman spectromety. Raman bands attributed to the components of the passivating film on the surface of the discharged Ag electrode, such as Li2CO3 and other species, were observed. No characteristic bands from discharged Al electrodes were present in the Raman spectra. This indicates that the Raman signals for the passivating layer are surface-enhanced by discharged Ag electrodes. The formation of a nanometer-scale rough surface caused by a Li-Ag alloy reaction during the discharging process is an important factor in the enhancement. It was also shown that the passivating films formed in various electrolytes could be distinguished by SERS. |
收录类别 | SCI |
语种 | 英语 |
公开日期 | 2013-09-24 |
源URL | [http://ir.iphy.ac.cn/handle/311004/54227] ![]() |
专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
推荐引用方式 GB/T 7714 | Li, H,Mo, YJ,Pei, N,et al. Surface-enhanced Raman scattering study on passivating films of Ag electrodes in lithium batteries[J]. JOURNAL OF PHYSICAL CHEMISTRY B,2000,104(35):8477. |
APA | Li, H,Mo, YJ,Pei, N,Xu, XX,Huang, XJ,&Chen, LQ.(2000).Surface-enhanced Raman scattering study on passivating films of Ag electrodes in lithium batteries.JOURNAL OF PHYSICAL CHEMISTRY B,104(35),8477. |
MLA | Li, H,et al."Surface-enhanced Raman scattering study on passivating films of Ag electrodes in lithium batteries".JOURNAL OF PHYSICAL CHEMISTRY B 104.35(2000):8477. |
入库方式: OAI收割
来源:物理研究所
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