Syntheses, crystal structure and magnetic properties of Rm+nCo5m+3nB2n
文献类型:期刊论文
作者 | Liang, JK ; Chen, Y ; Chen, XL |
刊名 | PROGRESS IN NATURAL SCIENCE
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出版日期 | 2001 |
卷号 | 11期号:12页码:881 |
关键词 | CO-B PHASE RELATION PERMANENT-MAGNETS ND BORIDES SM GD FE |
ISSN号 | 1002-0071 |
通讯作者 | Liang, JK (reprint author), Chinese Acad Sci, Inst Phys, POB 603, Beijing 100080, Peoples R China. |
中文摘要 | The phase relations at the 600 degreesC and 700 degreesC isothermal sections of the ternary systems R-Co-B for R Nd, Pr and R = Sm, Cd respectively were summarized in this paper. For Rm+nCo5m+3nB2n, two new types of compounds R3Co13B2 ( R = Pr, Nd, Sm, Gd, Dy, Ho, Er, Y) (m = 2, n = 1) and R5Co19B6 (R = Pr, Nd) (m = 2, n = 3) were synthesized by utilizing the principle of structural combination. Their crystal* structures and easy magnetization direction were determined by X-ray powder diffraction, and structures were refined by the Rietveld method. The Curie temperature T-C, saturation magnetization M-s and anisotropic field H-A of the new compounds were measured using a vibrating-sample magnetometer, an extraction sample magnetometer and M(H) - H curves of samples in different magnetization directions respectively. The T-C and M-s of Rm+nCo5m+3nB2n increase with increasing values of m at a given n value. H-A increases with an increase in n when m is kept invariable. The effects of the substitution of Ni for Co on the magnetic properties of Nd13Co15-xNixB2 were also investigated. It was found that T-SR decreased monotonously as the concentration of Ni increased, and at x = 3 the easy magnetization direction becomes axial at room temperature. The relations between crystal structure and magnetic properties of Rm+nCo5m+3nB2n and the possible routes of synthesizing permanent magnetic materials are also discussed. |
收录类别 | SCI |
语种 | 英语 |
公开日期 | 2013-09-24 |
源URL | [http://ir.iphy.ac.cn/handle/311004/54280] ![]() |
专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
推荐引用方式 GB/T 7714 | Liang, JK,Chen, Y,Chen, XL. Syntheses, crystal structure and magnetic properties of Rm+nCo5m+3nB2n[J]. PROGRESS IN NATURAL SCIENCE,2001,11(12):881. |
APA | Liang, JK,Chen, Y,&Chen, XL.(2001).Syntheses, crystal structure and magnetic properties of Rm+nCo5m+3nB2n.PROGRESS IN NATURAL SCIENCE,11(12),881. |
MLA | Liang, JK,et al."Syntheses, crystal structure and magnetic properties of Rm+nCo5m+3nB2n".PROGRESS IN NATURAL SCIENCE 11.12(2001):881. |
入库方式: OAI收割
来源:物理研究所
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