Synthesis and electrochemical performance of spinel LiMn2-x-yNixCryO4 as 5-V cathode materials for lithium ion batteries
文献类型:期刊论文
作者 | Sun, Y ; Wang, Z ; Huang, XJ ; Chen, LQ |
刊名 | JOURNAL OF POWER SOURCES
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出版日期 | 2004 |
卷号 | 132期号:1-2页码:161 |
关键词 | LICRYMN2-YO4 0-LESS-THAN-OR-EQUAL-TO-Y-LESS-THAN-OR-EQUAL-TO-1 COMPOUNDS POSITIVE-ELECTRODE MATERIALS SUPERFICIAL PROCESSES CR CONTENT LIMN2O4 VOLTAGE CELLS BEHAVIOR METAL BULK |
ISSN号 | 0378-7753 |
通讯作者 | Chen, LQ (reprint author), Chinese Acad Sci, Inst Phys, Lab Nanoscale Phys & Devices, POB 603, Beijing 100080, Peoples R China. |
中文摘要 | A series of spinel-structured LiMn2-x-yNixCryO4 have been prepared and their electrochemical performances as 5-V cathode materials for lithium ion batteries are evaluated. The synthesis reactions for these materials are characterized by TG/DSC, XRD and SEM. TG/DSC measurements show that the chemical reactions for the final product are completed below 400degreesC. XRD analysis indicates that spinel structure is formed at around 650degreesC. However, SEM images show well-defined polyhedron crystalline particles do not appear until 800degreesC. Electrochemical evaluation shows that LiMn1.4Ni0.4Cr0.2O4 prepared at 850degreesC boasts the best electrochemical performance with an initial discharge capacity of 128 mA h/g and a capacity retention of more than 90% after 230 cycles between 3.5 and 4.98 V (C) 2004 Elsevier B.V. All rights reserved. |
收录类别 | SCI |
语种 | 英语 |
公开日期 | 2013-09-24 |
源URL | [http://ir.iphy.ac.cn/handle/311004/54341] ![]() |
专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
推荐引用方式 GB/T 7714 | Sun, Y,Wang, Z,Huang, XJ,et al. Synthesis and electrochemical performance of spinel LiMn2-x-yNixCryO4 as 5-V cathode materials for lithium ion batteries[J]. JOURNAL OF POWER SOURCES,2004,132(1-2):161. |
APA | Sun, Y,Wang, Z,Huang, XJ,&Chen, LQ.(2004).Synthesis and electrochemical performance of spinel LiMn2-x-yNixCryO4 as 5-V cathode materials for lithium ion batteries.JOURNAL OF POWER SOURCES,132(1-2),161. |
MLA | Sun, Y,et al."Synthesis and electrochemical performance of spinel LiMn2-x-yNixCryO4 as 5-V cathode materials for lithium ion batteries".JOURNAL OF POWER SOURCES 132.1-2(2004):161. |
入库方式: OAI收割
来源:物理研究所
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