Synthesis and solid-state NMR structural characterization of (13)C-labeled graphite oxide
文献类型：期刊论文
| 作者 | Cai, WW ; Piner, RD ; Stadermann, FJ ; Park, S ; Shaibat, MA ; Ishii, Y ; Yang, DX ; Velamakanni, A ; An, SJ ; Stoller, M ; An, JH ; Chen, DM ; Ruoff, RS |
| 刊名 | SCIENCE
 |
| 出版日期 | 2008 |
| 卷号 | 321期号:5897页码:1815 |
| 关键词 | CARBON FORMATION GRAPHENE SURFACE GROWTH NICKEL NANOPLATELETS PRECIPITATION REDUCTION OXIDATION LAYERS |
| ISSN号 | 0036-8075 |
| 通讯作者 | Ruoff, RS (reprint author), Univ Texas Austin, Dept Mech Engn, Austin, TX 78712 USA. |
| 中文摘要 | The detailed chemical structure of graphite oxide ( GO), a layered material prepared from graphite almost 150 years ago and a precursor to chemically modified graphenes, has not been previously resolved because of the pseudo- random chemical functionalization of each layer, as well as variations in exact composition. Carbon-13 ((13)C) solid- state nuclear magnetic resonance ( SSNMR) spectra of GO for natural abundance (13)C have poor signal- to- noise ratios. Approximately 100% (13)C- labeled graphite was made and converted to (13)C- labeled GO, and (13)C SSNMR was used to reveal details of the chemical bonding network, including the chemical groups and their connections. Carbon-13-labeled graphite can be used to prepare chemically modified graphenes for (13)C SSNMR analysis with enhanced sensitivity and for fundamental studies of (13)C-labeled graphite and graphene. |
| 收录类别 | SCI |
| 资助信息 | Cambridge Isotopes Laboratories, Inc; Defense Advanced Research Projects Agency Center on Nanoscale Science and Technology for Integrated Micro/NanoElectromechanical Transducers [HR0011-06-1-0048]; Defense University Research Instrumentation Program; Dreyfus Foundation Teacher-Scholar Award program; NSF CAREER program [CHE 449952]; Korea Science and Engineering Foundation; National Creative Research Initiative Project [R16-2004-00401001-0]; Ministry of Science and Technology, Korea |
| 语种 | 英语 |
| 公开日期 | 2013-09-24 |
| 源URL | [http://ir.iphy.ac.cn/handle/311004/54393]  |
| 专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
| 推荐引用方式 GB/T 7714 | Cai, WW,Piner, RD,Stadermann, FJ,et al. Synthesis and solid-state NMR structural characterization of (13)C-labeled graphite oxide[J]. SCIENCE,2008,321(5897):1815. |
| APA | Cai, WW.,Piner, RD.,Stadermann, FJ.,Park, S.,Shaibat, MA.,...&Ruoff, RS.(2008).Synthesis and solid-state NMR structural characterization of (13)C-labeled graphite oxide.SCIENCE,321(5897),1815. |
| MLA | Cai, WW,et al."Synthesis and solid-state NMR structural characterization of (13)C-labeled graphite oxide".SCIENCE 321.5897(2008):1815. |
入库方式： OAI收割
来源：物理研究所
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