Synthesis and structure of 12-member ring crown-shaped oxovanadium borophosphate polyanions: [H(3)NC(2)H(4)NH(2)C(2)H(4)NH(2)C(2)H(4)NH(3)](4)H[M(VO)(12)-{O(3)POB(O)(2)OPO(3)}(6)]center dot nH(2)O (M = NH(4)(+), K(+))
文献类型：期刊论文
| 作者 | Zhao, YN ; Shi, Z ; Ding, SH ; Bai, N ; Liu, W ; Zou, YC ; Zhu, GS ; Zhang, P ; Mai, ZH ; Pang, WQ |
| 刊名 | CHEMISTRY OF MATERIALS
 |
| 出版日期 | 2000 |
| 卷号 | 12期号:9页码:2550 |
| 关键词 | GROUP OXIDE CLUSTER CRYSTAL-STRUCTURE HYDROTHERMAL SYNTHESIS VANADIUM PHOSPHATES BORATE-PHOSPHATE SYSTEM ALUMINOPHOSPHATE CHEMISTRY SOLIDS PHASES |
| ISSN号 | 0897-4756 |
| 通讯作者 | Zhao, YN (reprint author), Chinese Acad Sci, Inst Phys, POB 603, Beijing 100080, Peoples R China. |
| 中文摘要 | Using multiethylenemultiamine to direct the crystallization of inorganic frameworks through multipoint hydrogen bonds, two new oxovanadium borophosphates, denoted VBP-J1 and VBP-J2, have been synthesized by hydrothermal methods as well as under reflux conditions. Powder X-ray diffraction patterns indicate that VBP-J1 and VBP-J2 are structural analogues. Structure determinations show that both VBP-J1, [H(3)NC(2)H(4)NH(2)C(2)H(4)NH(2)C(2)H(4)NH(3)](4)H[NH(4)(VO)(12){O(3)POB(O)(2)OPO(3)}(6)]. 14H(2)O and VBP-J2, [H(3)NC(2)H(4)NH(2)C(2)H(4)NH(2)C(2)H(4)NH(3)](4)H[K(VO)(12){O(3)POB(O)(2)OPO(3)}(6)]. 16H(2)O crystallize in the orthorhombic space group Pbca with crystal data: a = 21.454(11) Angstrom, b = 16.315(6) Angstrom, c = 29.651(12) Angstrom, alpha = beta = gamma = 90 degrees, V = 10378(8) Angstrom(3), Z = 4 for VBP-J1 and a = 21.537(2) Angstrom, b = 16.2667(13) Angstrom, c = 29.717(4) Angstrom, alpha = beta = gamma = 90 degrees, V = 10410.8(18) Angstrom(3), Z = 4 for VBP-J2. VBP-J1 and VBP-J2 are constructed by edge-sharing {V(2)O(10)} binuclear unit and {BP(2)O(10)} trimer to form interesting 12-member ring crown-shaped clusters with NH(4)(+) and K(+) cations encapsulated in the clusters. The ring diameters are 5.873 x 5.412 x 5.561 Angstrom for VBP-J1 and 5.758 x 5.421 x 5.236 Angstrom for VBP-J2. An extended network of multiple hydrogen bands among anions, cations, and water molecules links the structure in three dimensions. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2013-09-24 |
| 源URL | [http://ir.iphy.ac.cn/handle/311004/54400]  |
| 专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
| 推荐引用方式 GB/T 7714 | Zhao, YN,Shi, Z,Ding, SH,et al. Synthesis and structure of 12-member ring crown-shaped oxovanadium borophosphate polyanions: [H(3)NC(2)H(4)NH(2)C(2)H(4)NH(2)C(2)H(4)NH(3)](4)H[M(VO)(12)-{O(3)POB(O)(2)OPO(3)}(6)]center dot nH(2)O (M = NH(4)(+), K(+))[J]. CHEMISTRY OF MATERIALS,2000,12(9):2550. |
| APA | Zhao, YN.,Shi, Z.,Ding, SH.,Bai, N.,Liu, W.,...&Pang, WQ.(2000).Synthesis and structure of 12-member ring crown-shaped oxovanadium borophosphate polyanions: [H(3)NC(2)H(4)NH(2)C(2)H(4)NH(2)C(2)H(4)NH(3)](4)H[M(VO)(12)-{O(3)POB(O)(2)OPO(3)}(6)]center dot nH(2)O (M = NH(4)(+), K(+)).CHEMISTRY OF MATERIALS,12(9),2550. |
| MLA | Zhao, YN,et al."Synthesis and structure of 12-member ring crown-shaped oxovanadium borophosphate polyanions: [H(3)NC(2)H(4)NH(2)C(2)H(4)NH(2)C(2)H(4)NH(3)](4)H[M(VO)(12)-{O(3)POB(O)(2)OPO(3)}(6)]center dot nH(2)O (M = NH(4)(+), K(+))".CHEMISTRY OF MATERIALS 12.9(2000):2550. |
入库方式： OAI收割
来源：物理研究所
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