Synthesis and structure of an open-framework cobalt zincophosphate
文献类型：期刊论文
| 作者 | Chen, XM ; Zhao, YN ; Wang, RJ ; Ming, LA ; Mai, ZH |
| 刊名 | JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
 |
| 出版日期 | 2002 |
| 期号 | 16页码:3092 |
| 关键词 | ZINC PHOSPHATE GALLIUM PHOSPHATE SOLVOTHERMAL SYNTHESIS HYDROTHERMAL SYNTHESIS MOLECULAR-SIEVES METAL PHOSPHATES TETRAHEDRA ROUTE |
| ISSN号 | 1472-7773 |
| 通讯作者 | Zhao, YN (reprint author), Chinese Acad Sci, Inst Phys, POB 603, Beijing 100080, Peoples R China. |
| 中文摘要 | Introducing cobalt into a Zn-P-O-amine system and using oxalates as starting materials, an amine containing open-framework cobalt zincophosphate, [C4N2H12][Co0.14Zn1.86(PO4)(H1.5PO4)(2)] (1), has been hydrothermally synthesized and structurally determined. It crystallizes in the monoclinic space group C2/c (No. 15) with cell parameters a = 13.374(3) Angstrom, b = 12.827(3) Angstrom, c = 8.1940(16) Angstrom, beta = 94.77(3)degrees, V = 1400.9(5) Angstrom(3), Z = 4, D-cal = 2.399 g cm(-3). The linkages of ZnO4 and PO4 give rise to four-membered rings, which serve as the secondary building unit for compound 1. The four-membered rings (four-MR) share their corners leading to chains. Connection of these chains results in a complex three-dimensional channel system. Eight-MR, twelve-MR and highly distorted twelve-MR channels can be observed along the [010], [110] and [101] directions, respectively. The prominent feature of compound 1 is the clover-like 16-MR channel along the [001] direction. The channel spaces are occupied by the diprotonated piperazine molecules with H-bonds to the framework. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2013-09-24 |
| 源URL | [http://ir.iphy.ac.cn/handle/311004/54401]  |
| 专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
| 推荐引用方式 GB/T 7714 | Chen, XM,Zhao, YN,Wang, RJ,et al. Synthesis and structure of an open-framework cobalt zincophosphate[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS,2002(16):3092. |
| APA | Chen, XM,Zhao, YN,Wang, RJ,Ming, LA,&Mai, ZH.(2002).Synthesis and structure of an open-framework cobalt zincophosphate.JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS(16),3092. |
| MLA | Chen, XM,et al."Synthesis and structure of an open-framework cobalt zincophosphate".JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS .16(2002):3092. |
入库方式： OAI收割
来源：物理研究所
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