Synthesis of High-Quality Brookite TiO2 Single-Crystalline Nanosheets with Specific Facets Exposed: Tuning Catalysts from Inert to Highly Reactive
文献类型：期刊论文
| 作者 | Lin, HF ; Li, LP ; Zhao, ML ; Huang, XS ; Chen, XM ; Li, GS ; Yu, RC |
| 刊名 | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
 |
| 出版日期 | 2012 |
| 卷号 | 134期号:20页码:8328 |
| 关键词 | TITANIUM-DIOXIDE SELECTIVE SYNTHESIS SURFACE SCIENCE ANATASE RUTILE NANOCRYSTALS NANORODS NANOPARTICLES |
| ISSN号 | 0002-7863 |
| 通讯作者 | Li, GS (reprint author), Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China. |
| 中文摘要 | The brookite phase of TiO2 is hardly prepared and rarely studied in comparison with the common anatase and rutile phases. In addition, there exist immense controversies over the cognition of the light-induced liveliness of this material. Here, a novel, low-basicity solution chemistry method was first used to prepare homogeneous high-quality broolcite TiO2 single-crystalline nanosheets surrounded with four {210}, two {101}, and two {201} facets. These nanosheets exhibited outstanding activity toward the catalytic degradation of organic contaminants superior even to that of Degussa P25, due to the exposure of high-energy facets and the effective suppression of recombination rates of photo-generated electrons and holes by these facets as the oxidative and reductive sites. In contrast, irregularly faceted phase-pure brookite nanoflowers and nanospindles were inactive in catalytic reactions. These results demonstrate that the photocatalytic activity of brookite TiO2 is highly dependent upon its exposed facets, which offers a strategy for tuning the catalysts from inert to highly active through tailoring of the morphology and surface structure. |
| 收录类别 | SCI |
| 资助信息 | National Natural Science Foundation of China [21025104, 91022018, 51072198]; Ministry of Science and Technology of China [2011CBA00501] |
| 语种 | 英语 |
| 公开日期 | 2013-09-24 |
| 源URL | [http://ir.iphy.ac.cn/handle/311004/54438]  |
| 专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
| 推荐引用方式 GB/T 7714 | Lin, HF,Li, LP,Zhao, ML,et al. Synthesis of High-Quality Brookite TiO2 Single-Crystalline Nanosheets with Specific Facets Exposed: Tuning Catalysts from Inert to Highly Reactive[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2012,134(20):8328. |
| APA | Lin, HF.,Li, LP.,Zhao, ML.,Huang, XS.,Chen, XM.,...&Yu, RC.(2012).Synthesis of High-Quality Brookite TiO2 Single-Crystalline Nanosheets with Specific Facets Exposed: Tuning Catalysts from Inert to Highly Reactive.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,134(20),8328. |
| MLA | Lin, HF,et al."Synthesis of High-Quality Brookite TiO2 Single-Crystalline Nanosheets with Specific Facets Exposed: Tuning Catalysts from Inert to Highly Reactive".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 134.20(2012):8328. |
入库方式： OAI收割
来源：物理研究所
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