A new class of Solvent-in-Salt electrolyte for high-energy rechargeable metallic lithium batteries
文献类型：期刊论文
| 作者 | Suo, LM ; Hu, YS ; Li, H ; Armand, M ; Chen, LQ |
| 刊名 | NATURE COMMUNICATIONS
 |
| 出版日期 | 2013 |
| 卷号 | 4 |
| ISSN号 | 2041-1723 |
| 通讯作者 | Hu, YS (reprint author), Chinese Acad Sci, Key Lab Renewable Energy, Beijing Key Lab New Energy Mat & Devices, Beijing Natl Lab Condensed Matter Phys,Inst Phys, Beijing 100190, Peoples R China. |
| 中文摘要 | Liquid electrolyte plays a key role in commercial lithium-ion batteries to allow conduction of lithium-ion between cathode and anode. Traditionally, taking into account the ionic conductivity, viscosity and dissolubility of lithium salt, the salt concentration in liquid electrolytes is typically less than 1.2 mol l(-1). Here we show a new class of 'Solvent-in-Salt' electrolyte with ultrahigh salt concentration and high lithium-ion transference number (0.73), in which salt holds a dominant position in the lithium-ion transport system. It remarkably enhances cyclic and safety performance of next-generation high-energy rechargeable lithium batteries via an effective suppression of lithium dendrite growth and shape change in the metallic lithium anode. Moreover, when used in lithium-sulphur battery, the advantage of this electrolyte is further demonstrated that lithium polysulphide dissolution is inhibited, thus overcoming one of today's most challenging technological hurdles, the 'polysulphide shuttle phenomenon'. Consequently, a coulombic efficiency nearing 100% and long cycling stability are achieved. |
| 资助信息 | '863' Project [2009AA033101]; '973' Projects [2009CB220104]; NSFC [50972164, 51222210]; CAS project [KJCX2-YW-W26]; One Hundred Talent Project of the Chinese Academy of Sciences |
| 语种 | 英语 |
| 公开日期 | 2014-01-16 |
| 源URL | [http://ir.iphy.ac.cn/handle/311004/56727]  |
| 专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
| 推荐引用方式 GB/T 7714 | Suo, LM,Hu, YS,Li, H,et al. A new class of Solvent-in-Salt electrolyte for high-energy rechargeable metallic lithium batteries[J]. NATURE COMMUNICATIONS,2013,4. |
| APA | Suo, LM,Hu, YS,Li, H,Armand, M,&Chen, LQ.(2013).A new class of Solvent-in-Salt electrolyte for high-energy rechargeable metallic lithium batteries.NATURE COMMUNICATIONS,4. |
| MLA | Suo, LM,et al."A new class of Solvent-in-Salt electrolyte for high-energy rechargeable metallic lithium batteries".NATURE COMMUNICATIONS 4(2013). |
入库方式： OAI收割
来源：物理研究所
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