An FeF3 center dot 0.5H(2)O Polytype: A Microporous Framework Compound with Intersecting Tunnels for Li and Na Batteries
文献类型：期刊论文
| 作者 | Li, CL ; Yin, CL ; Gu, L ; Dinnebier, RE ; Mu, XK ; van Aken, PA ; Maier, J |
| 刊名 | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
 |
| 出版日期 | 2013 |
| 卷号 | 135期号:31页码:11425 |
| ISSN号 | 0002-7863 |
| 通讯作者 | Li, CL (reprint author), Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, Shanghai 200050, Peoples R China. |
| 中文摘要 | To improve the energy/power density of energy storage materials, numerous efforts have focused on the exploration of new structure prototypes, in particular metal-organic fameworks, Prussian blue analogues, open-framework oxides, and polyanion salts. Here we report a novel pyrochlore phase that appears to be useful as a high-capacity cathode for Li and Na batteries. It is an iron fluoride polymorph characterized by an intersecting tunnel structure, providing the space for accommodation and transport of Li and Na ions. It is prepared using hydrolyzable ionic liquids, which serve as reaction educts and structure-directing agents not only as far as the chemical structure is concerned but also in terms of morphology (shape, defect structure, electrode network structure). A capacity higher than 220 mA h g(-1) (for Li and Na storage) and a lifetime of at least 300 cycles (for Li storage) are demonstrated. |
| 资助信息 | Hundred Talents Program of the Chinese Academy of Sciences |
| 语种 | 英语 |
| 公开日期 | 2014-01-16 |
| 源URL | [http://ir.iphy.ac.cn/handle/311004/56770]  |
| 专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
| 推荐引用方式 GB/T 7714 | Li, CL,Yin, CL,Gu, L,et al. An FeF3 center dot 0.5H(2)O Polytype: A Microporous Framework Compound with Intersecting Tunnels for Li and Na Batteries[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2013,135(31):11425. |
| APA | Li, CL.,Yin, CL.,Gu, L.,Dinnebier, RE.,Mu, XK.,...&Maier, J.(2013).An FeF3 center dot 0.5H(2)O Polytype: A Microporous Framework Compound with Intersecting Tunnels for Li and Na Batteries.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,135(31),11425. |
| MLA | Li, CL,et al."An FeF3 center dot 0.5H(2)O Polytype: A Microporous Framework Compound with Intersecting Tunnels for Li and Na Batteries".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 135.31(2013):11425. |
入库方式： OAI收割
来源：物理研究所
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