Electrospinning La0.8Sr0.2Co0.2Fe0.8O3-delta tubes impregnated with Ce0.8Gd0.2O1.9 nanoparticles for an intermediate temperature solid oxide fuel cell cathode
文献类型：期刊论文
| 作者 | Zhao, EQ ; Ma, C ; Yang, W ; Xiong, YP ; Li, JQ ; Sun, CW |
| 刊名 | INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
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| 出版日期 | 2013 |
| 卷号 | 38期号:16页码:6821 |
| 关键词 | La0.8Sr0.2Co0.2Fe0.8O3-delta Ce0.8Gd0.2O1.9 Composite cathode Electrospinning Impregnation Intermediate temperature solid oxide fuel cell |
| ISSN号 | 0360-3199 |
| 通讯作者 | Xiong, YP (reprint author), Harbin Inst Technol, Sch Chem Engn & Technol, Mailbox 1247,92 West Dazhi St, Harbin 150001, Peoples R China. |
| 中文摘要 | In order to reduce the polarization resistance of the cathode, we have developed one-dimensional (1D) nanostructured La0.8Sr0.2Co0.2Fe0.8O3-delta (LSCF) tubes/Ce0.8Gd0.2O1.9 (GDC) nanoparticles composite cathodes for solid oxide fuel cell. Uniform LSCF/PVP composite nanofibers have been firstly synthesized by a single-nozzle electrospinning technique, followed by firing at 800 degrees C for 2 h to form one-dimensional LSCF tubes. Subsequently, the GDC phases were introduced into tube structured LSCF scaffold pre-sintered on a GDC pellet by a multi-impregnation process. Electrochemical Impedance spectra reveal that nanostructured LSCF tubes/GDC nanoparticles composite cathodes have a better electrochemical performance, achieving area-specific resistances of 4.70, 1.12, 0.27 and 0.07 Omega cm(2) at 500, 550, 600 and 650 degrees C for the composite of GDC and LSCF in a weight ratio of 0.52:1. The low ASR values are mainly related to its optimal microstructure with larger triple-phase boundaries and higher porosity. These results suggest that LSCF tube/GDC nanoparticle composite can be an alternative cathode material for intermediate temperature solid oxide fuel cell (IT-SOFC). Copyright (C) 2013, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved. |
| 资助信息 | National Natural Science Foundation [51072040]; National Program on Key Basic Research Project (973 Program) [2012CB215400]; National Science Foundation of China [51172275, 11004229] |
| 语种 | 英语 |
| 公开日期 | 2014-01-16 |
| 源URL | [http://ir.iphy.ac.cn/handle/311004/56959]  |
| 专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
| 推荐引用方式 GB/T 7714 | Zhao, EQ,Ma, C,Yang, W,et al. Electrospinning La0.8Sr0.2Co0.2Fe0.8O3-delta tubes impregnated with Ce0.8Gd0.2O1.9 nanoparticles for an intermediate temperature solid oxide fuel cell cathode[J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,2013,38(16):6821. |
| APA | Zhao, EQ,Ma, C,Yang, W,Xiong, YP,Li, JQ,&Sun, CW.(2013).Electrospinning La0.8Sr0.2Co0.2Fe0.8O3-delta tubes impregnated with Ce0.8Gd0.2O1.9 nanoparticles for an intermediate temperature solid oxide fuel cell cathode.INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,38(16),6821. |
| MLA | Zhao, EQ,et al."Electrospinning La0.8Sr0.2Co0.2Fe0.8O3-delta tubes impregnated with Ce0.8Gd0.2O1.9 nanoparticles for an intermediate temperature solid oxide fuel cell cathode".INTERNATIONAL JOURNAL OF HYDROGEN ENERGY 38.16(2013):6821. |
入库方式： OAI收割
来源：物理研究所
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