Graphite microspheres decorated with Si particles derived from waste solid of organosilane industry as high capacity anodes for Li-ion batteries
文献类型：期刊论文
| 作者 | Yu, J ; Zhan, HH ; Wang, YH ; Zhang, ZLI ; Chen, H ; Li, H ; Zhong, ZY ; Su, FB |
| 刊名 | JOURNAL OF POWER SOURCES
 |
| 出版日期 | 2013 |
| 卷号 | 228页码:112 |
| 关键词 | Silicon waste Graphite Silicon/carbon composite anode Lithium-ion batteries Electrochemical performance |
| ISSN号 | 0378-7753 |
| 通讯作者 | Wang, YH (reprint author), Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China. |
| 中文摘要 | We report the decoration of commercial graphite microspheres (GMs) with Si particles as anode materials for Li-ion batteries. The Si particles are obtained from solid Si waste of organosilane industry that is acid-washed to remove the impurities and further ground. The GMs with a size of 5-40 mu m as main active material, Si particles with a size of 1-10 mu m as an additive, and sucrose dissolved in water as a binder are mixed and followed by carbonization to obtain Si/C composites containing graphite, Si, and amorphous carbon generated from sucrose. It is found that the composite containing 60.5 wt% of GMs, 22.1 wt% of Si, and 17.4 wt% of amorphous carbon obtained at 800 degrees C for 5 h shows the best electrochemical performance with a specific capacity of 522.6 mA h g(-1) at the current density of 50 mA g(-1) and 306.9 mA h g(-1) at 500 mA g(-1), much higher than those of GMs. Its capacity retention at 500 mA g(-1) attains 93.9% after 20 cycles. The work demonstrates the possibility for utilization of the industrial Si waste to enhance graphite anode materials in Li-ion batteries. (C) 2012 Elsevier B.V. All rights reserved. |
| 资助信息 | National Natural Science Foundation of China [51272252]; State Key Laboratory of Multiphase Complex Systems [MPCS-2012-A-09]; Hundred Talents Program of the Chinese Academy of Sciences; Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD) [SA1102]; Fundamental Research Funds for the Central Universities [2012LWB29] |
| 语种 | 英语 |
| 公开日期 | 2014-01-16 |
| 源URL | [http://ir.iphy.ac.cn/handle/311004/57051]  |
| 专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
| 推荐引用方式 GB/T 7714 | Yu, J,Zhan, HH,Wang, YH,et al. Graphite microspheres decorated with Si particles derived from waste solid of organosilane industry as high capacity anodes for Li-ion batteries[J]. JOURNAL OF POWER SOURCES,2013,228:112. |
| APA | Yu, J.,Zhan, HH.,Wang, YH.,Zhang, ZLI.,Chen, H.,...&Su, FB.(2013).Graphite microspheres decorated with Si particles derived from waste solid of organosilane industry as high capacity anodes for Li-ion batteries.JOURNAL OF POWER SOURCES,228,112. |
| MLA | Yu, J,et al."Graphite microspheres decorated with Si particles derived from waste solid of organosilane industry as high capacity anodes for Li-ion batteries".JOURNAL OF POWER SOURCES 228(2013):112. |
入库方式： OAI收割
来源：物理研究所
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