Improved electrochemical properties of MnO thin film anodes by elevated deposition temperatures: Study of conversion reactions
文献类型：期刊论文
| 作者 | Cui, ZH ; Guo, XX ; Li, H |
| 刊名 | ELECTROCHIMICA ACTA
 |
| 出版日期 | 2013 |
| 卷号 | 89页码:229 |
| 关键词 | MnO thin film anodes Conversion reactions Lithium ion batteries Electrochemical properties |
| ISSN号 | 0013-4686 |
| 通讯作者 | Guo, XX (reprint author), Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, Shanghai 200050, Peoples R China. |
| 中文摘要 | MnO thin films were grown on Cu-foil substrates at various temperatures by the pulsed laser deposition (PLO) technique. The elevated growth temperatures led to the improved storage capacity, initial Coulombic efficiency and rate performance of the thin film anodes. It also had an observable effect on the voltage polarization at the first discharge process, whereas negligible at the subsequent cycles. The origins for these behaviours were clarified. The superior electrochemical performance was attributed to the improved kinetic properties, which relate to the initial better crystallinity and more ordered microstructure of the films caused by the elevated deposition temperatures. The similar behaviour of voltage polarization in the cycles after the first discharge was ascribed to the similar nanocomposited structure induced by the initial conversion reaction. Moreover, the mechanisms for the low initial Coulombic efficiency and the large voltage polarization, which are the appealing and essential topics for the conversion reactions, were elucidated. (C) 2012 Elsevier Ltd. All rights reserved. |
| 资助信息 | NSFC [10979069, U1232111]; "Hundred Talent Program" of Chinese Academy of Sciences |
| 语种 | 英语 |
| 公开日期 | 2014-01-16 |
| 源URL | [http://ir.iphy.ac.cn/handle/311004/57100]  |
| 专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
| 推荐引用方式 GB/T 7714 | Cui, ZH,Guo, XX,Li, H. Improved electrochemical properties of MnO thin film anodes by elevated deposition temperatures: Study of conversion reactions[J]. ELECTROCHIMICA ACTA,2013,89:229. |
| APA | Cui, ZH,Guo, XX,&Li, H.(2013).Improved electrochemical properties of MnO thin film anodes by elevated deposition temperatures: Study of conversion reactions.ELECTROCHIMICA ACTA,89,229. |
| MLA | Cui, ZH,et al."Improved electrochemical properties of MnO thin film anodes by elevated deposition temperatures: Study of conversion reactions".ELECTROCHIMICA ACTA 89(2013):229. |
入库方式： OAI收割
来源：物理研究所
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