New Layered Iron Sulfide NaFe1.6S2: Synthesis and Characterization
文献类型：期刊论文
| 作者 | Lai, XF ; Chen, XL ; Jin, SF ; Wang, G ; Zhou, TT ; Ying, TP ; Zhang, H ; Shen, SJ ; Wang, WY |
| 刊名 | INORGANIC CHEMISTRY
 |
| 出版日期 | 2013 |
| 卷号 | 52期号:22页码:12860 |
| ISSN号 | 0020-1669 |
| 通讯作者 | Chen, XL (reprint author), Chinese Acad Sci, Res & Dev Ctr Funct Crystals, Beijing Natl Lab Condensed Matter Phys, Inst Phys, POB 603, Beijing 100190, Peoples R China. |
| 中文摘要 | Na was intercalated between [Fe2S2] layers for the first time, giving a novel compound NaFe1.6S2. This material adopts a CaAl2Si2-type structure with similar to 20% iron vacancies and represents the first layered compound in a ternary Na-M-X (M = Fe, Co, Ni; X = S, Se) system. First-principles calculations reveal that phonon dynamics is an important factor for it to prefer the CaAl2Si2-type rather than the ThCr2Si2-type structure. It features a magnetic transition at 205 K and is a narrow-band-gap semiconductor. |
| 资助信息 | National Natural Science Foundation of China [90922037, 51072226, 51202286]; International Center for Diffraction Data |
| 语种 | 英语 |
| 公开日期 | 2014-01-16 |
| 源URL | [http://ir.iphy.ac.cn/handle/311004/57247]  |
| 专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
| 推荐引用方式 GB/T 7714 | Lai, XF,Chen, XL,Jin, SF,et al. New Layered Iron Sulfide NaFe1.6S2: Synthesis and Characterization[J]. INORGANIC CHEMISTRY,2013,52(22):12860. |
| APA | Lai, XF.,Chen, XL.,Jin, SF.,Wang, G.,Zhou, TT.,...&Wang, WY.(2013).New Layered Iron Sulfide NaFe1.6S2: Synthesis and Characterization.INORGANIC CHEMISTRY,52(22),12860. |
| MLA | Lai, XF,et al."New Layered Iron Sulfide NaFe1.6S2: Synthesis and Characterization".INORGANIC CHEMISTRY 52.22(2013):12860. |
入库方式： OAI收割
来源：物理研究所
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