Supramolecular assembly of Keggin polyoxomolybdate and 2,2 '-bipyridine generated in situ from a decarboxylation coupling reaction
文献类型：期刊论文
| 作者 | Li, CH ; Wang, Q ; Chi, YN ; Wang, XF ; Hu, CW |
| 刊名 | CHINESE CHEMICAL LETTERS
 |
| 出版日期 | 2013 |
| 卷号 | 24期号:7页码:578 |
| 关键词 | Polyoxometalates Decarboxylation coupling In situ Photoluminescence |
| ISSN号 | 1001-8417 |
| 通讯作者 | Hu, CW (reprint author), Beijing Inst Technol, Minist Educ China, Sch Chem, Key Lab Cluster Sci, Beijing 100081, Peoples R China. |
| 中文摘要 | An assembly of Keggin polyoxomolybdate and organic substrate (Hbipy)(3)[PMo12O40] (1, bipy = 2,2'-bipyridine) was synthesized and characterized by elemental analysis, infrared spectrum, and single-crystal X-ray analysis. The ligand bipy of compound 1 was generated by a decarboxylation coupling reaction of H(2)pdc (H(2)pdc = pyridine-2,6-dicarboxylic acid) in situ under hydrothermal reaction conditions and the control experiments illustrate that La(NO3)(3) or Ce(NO3)(3), which does not appear in the final structure, is necessary for the decarboxylation coupling reaction. Moreover, compound 1 displays strong photoluminescence property in the solid state at room temperature. (c) 2013 Chang-Wen Hu. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved. |
| 资助信息 | National Natural Science Foundation of China [21173021, 21231002, 21276026, 20801036, 51002180]; 111 Project [B07012]; Program of Cooperation of the Beijing Education Commission [20091739006] |
| 语种 | 英语 |
| 公开日期 | 2014-01-17 |
| 源URL | [http://ir.iphy.ac.cn/handle/311004/57523]  |
| 专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
| 推荐引用方式 GB/T 7714 | Li, CH,Wang, Q,Chi, YN,et al. Supramolecular assembly of Keggin polyoxomolybdate and 2,2 '-bipyridine generated in situ from a decarboxylation coupling reaction[J]. CHINESE CHEMICAL LETTERS,2013,24(7):578. |
| APA | Li, CH,Wang, Q,Chi, YN,Wang, XF,&Hu, CW.(2013).Supramolecular assembly of Keggin polyoxomolybdate and 2,2 '-bipyridine generated in situ from a decarboxylation coupling reaction.CHINESE CHEMICAL LETTERS,24(7),578. |
| MLA | Li, CH,et al."Supramolecular assembly of Keggin polyoxomolybdate and 2,2 '-bipyridine generated in situ from a decarboxylation coupling reaction".CHINESE CHEMICAL LETTERS 24.7(2013):578. |
入库方式： OAI收割
来源：物理研究所
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