Effects of pitzer mixing parameters on the solubility prediction ofHCl-RbCl-H2O system at 25 degrees C
文献类型：期刊论文
| 作者 | Pan, H.Song, P.Han, Z.Li, Y.Li, WuXia, S. |
| 刊名 | RUSSIAN JOURNAL OF INORGANIC CHEMISTRY
 |
| 出版日期 | 2007 |
| 卷号 | 52期号:11页码:1803-1807 |
| ISSN号 | 0036-0236 |
| 中文摘要 | The calculated solubilities of the phase system HCl-RbCl-H2O at 25 degrees C when the Pitzer's mixing parameters theta(HRb) and psi(HRbCl) are changed by +10% and -10% are reported. The calculated results indicate that there is a great deviation between the experimental data and the calculated solubilities when the mixing parameters were varied. The influence of psi(RbHCl) in solubility prediction in the RbCl-HCl-H2O system is much stronger than that of theta(RbH). This study supplies a theoretical basis for the manufacturing process which was proposed by Gao and employed to extract LiCl, RbCl, and CsCl from salt lake brine. The calculated solubilities of the phase system HCl-RbCl-H2O at 25 degrees C when the Pitzer's mixing parameters theta(HRb) and psi(HRbCl) are changed by +10% and -10% are reported. The calculated results indicate that there is a great deviation between the experimental data and the calculated solubilities when the mixing parameters were varied. The influence of psi(RbHCl) in solubility prediction in the RbCl-HCl-H2O system is much stronger than that of theta(RbH). This study supplies a theoretical basis for the manufacturing process which was proposed by Gao and employed to extract LiCl, RbCl, and CsCl from salt lake brine. |
| 收录类别 | SCI |
| 公开日期 | 2014-02-21 |
| 源URL | [http://ir.isl.ac.cn/handle/363002/2280]  |
| 专题 | 青海盐湖研究所_青海盐湖研究所知识仓储 中国科学院青海盐湖研究所 |
| 推荐引用方式 GB/T 7714 | Pan, H.Song, P.Han, Z.Li, Y.Li, WuXia, S.. Effects of pitzer mixing parameters on the solubility prediction ofHCl-RbCl-H2O system at 25 degrees C[J]. RUSSIAN JOURNAL OF INORGANIC CHEMISTRY,2007,52(11):1803-1807. |
| APA | Pan, H.Song, P.Han, Z.Li, Y.Li, WuXia, S..(2007).Effects of pitzer mixing parameters on the solubility prediction ofHCl-RbCl-H2O system at 25 degrees C.RUSSIAN JOURNAL OF INORGANIC CHEMISTRY,52(11),1803-1807. |
| MLA | Pan, H.Song, P.Han, Z.Li, Y.Li, WuXia, S.."Effects of pitzer mixing parameters on the solubility prediction ofHCl-RbCl-H2O system at 25 degrees C".RUSSIAN JOURNAL OF INORGANIC CHEMISTRY 52.11(2007):1803-1807. |
入库方式： OAI收割
来源：青海盐湖研究所
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