An unexpected role of a trace amount of water in catalyzing protontransfer in phosphine-catalyzed (3+2) cycloaddition of allenoates andalkenes
文献类型：期刊论文
| 作者 | Xia, Yuanzhi ; Liang, YongChen, YuanyuanWang, Ming ; Jiao, Lei ; Huang, Feng ; Liu, Song ; Li, Yahong ; Yu, Zhi-Xiang |
| 刊名 | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
 |
| 出版日期 | 2007 |
| 卷号 | 129期号:12页码:3470- + |
| ISSN号 | 0002-7863 |
| 中文摘要 | Through the joint forces of computation and experiment, the detailed mechanism of the Lu phosphine catalyzed (3 + 2) cycloaddition of allenoates and alkenes has been elucidated. The overall potential energy surface of the Lu (3 + 2) reaction has been computed. More importantly, theory and experiment have confirmed that a trace amount of water plays a critical role in assisting the process of [1,2] proton shift in the Lu reaction. Through the joint forces of computation and experiment, the detailed mechanism of the Lu phosphine catalyzed (3 + 2) cycloaddition of allenoates and alkenes has been elucidated. The overall potential energy surface of the Lu (3 + 2) reaction has been computed. More importantly, theory and experiment have confirmed that a trace amount of water plays a critical role in assisting the process of [1,2] proton shift in the Lu reaction. |
| 英文摘要 | 英文摘要 |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2014-02-21 |
| 源URL | [http://ir.isl.ac.cn/handle/363002/2292]  |
| 专题 | 青海盐湖研究所_青海盐湖研究所知识仓储 中国科学院青海盐湖研究所 |
| 推荐引用方式 GB/T 7714 | Xia, Yuanzhi,Liang, YongChen, YuanyuanWang, Ming,Jiao, Lei,et al. An unexpected role of a trace amount of water in catalyzing protontransfer in phosphine-catalyzed (3+2) cycloaddition of allenoates andalkenes[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2007,129(12):3470- +. |
| APA | Xia, Yuanzhi.,Liang, YongChen, YuanyuanWang, Ming.,Jiao, Lei.,Huang, Feng.,Liu, Song.,...&Yu, Zhi-Xiang.(2007).An unexpected role of a trace amount of water in catalyzing protontransfer in phosphine-catalyzed (3+2) cycloaddition of allenoates andalkenes.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,129(12),3470- +. |
| MLA | Xia, Yuanzhi,et al."An unexpected role of a trace amount of water in catalyzing protontransfer in phosphine-catalyzed (3+2) cycloaddition of allenoates andalkenes".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 129.12(2007):3470- +. |
入库方式： OAI收割
来源：青海盐湖研究所
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