Electrochemical Properties and Regioselectivity of Cyclopalladation of Chiral Ferrocenylimines Deriving from (S)-Ferrocenylethylamine
文献类型：期刊论文
| 作者 | Yin, Zhigang1; Qian, Hengyu1; Wang, Quanling1; Dong, Huichao1; Yan, Shihai2; Zhang, Chunxia1; Li, Junhua1 |
| 刊名 | AUSTRALIAN JOURNAL OF CHEMISTRY
 |
| 出版日期 | 2013 |
| 卷号 | 66期号:2页码:218-226 |
| 中文摘要 | Treatment of a cyclopalladated complex derived from chiral ferrocenylimine (Z5-C5H5)Fe(Z5-C5H4)–CH(CH3)–N¼CH–2-C4H3S, (Sc)-1, with PPh3 produced the heteroannular palladacycle (Sc)-3 in which palladation occurred at the unsubstituted cyclopentadiene ring. While for (Z5-C5H5)Fe(Z5-C5H4)–CH(CH3)–N¼CH–C6H5, (Sc)-4, cyclopalladation took place mainly at the phenyl ring; the heteroannular palladacycle (Sc)-6, as a minor product, was also obtained. Single crystal X-ray analysis, electrochemical, and computational studies have been performed, showing good agreement with experimental results. |
| 英文摘要 | Treatment of a cyclopalladated complex derived from chiral ferrocenylimine (eta(5)-C5H5) Fe(eta(5)-C5H4)-CH(CH3)-N=CH-2-C4H3S, (Sc)-1, with PPh3 produced the heteroannular palladacycle (Sc)-3 in which palladation occurred at the unsubstituted cyclopentadiene ring. While for (eta(5)-C5H5)Fe(eta(5)-C5H4)-CH(CH3)-N=CH-C6H5, (Sc)-4, cyclopalladation took place mainly at the phenyl ring; the heteroannular palladacycle (Sc)-6, as a minor product, was also obtained. Single crystal X-ray analysis, electrochemical, and computational studies have been performed, showing good agreement with experimental results. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 学科主题 | 仿真与模拟 |
| 类目[WOS] | Chemistry, Multidisciplinary |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | AZA-CLAISEN REARRANGEMENT ; CRYSTAL-STRUCTURE ; STRUCTURAL-CHARACTERIZATION ; SCHIFF-BASES ; COMPLEXES ; BONDS ; PALLADACYCLES ; SUBSTITUTION ; ENANTIOPURE ; FERROCENE |
| 收录类别 | SCI ; IC |
| 语种 | 英语 |
| WOS记录号 | WOS:000314900000015 |
| 公开日期 | 2014-03-21 |
| 源URL | [http://ir.qibebt.ac.cn:8080/handle/337004/1637]  |
| 专题 | 青岛生物能源与过程研究所_仿真模拟团队 |
| 作者单位 | 1.Zhengzhou Univ Light Ind, Key Lab Surface& Interface Sci Henan, Sch Mat Chem Engn, Zhengzhou 450002, Peoples R China 2.Chinese Acad Sci, Lab Biofuel, Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yin, Zhigang,Qian, Hengyu,Wang, Quanling,et al. Electrochemical Properties and Regioselectivity of Cyclopalladation of Chiral Ferrocenylimines Deriving from (S)-Ferrocenylethylamine[J]. AUSTRALIAN JOURNAL OF CHEMISTRY,2013,66(2):218-226. |
| APA | Yin, Zhigang.,Qian, Hengyu.,Wang, Quanling.,Dong, Huichao.,Yan, Shihai.,...&Li, Junhua.(2013).Electrochemical Properties and Regioselectivity of Cyclopalladation of Chiral Ferrocenylimines Deriving from (S)-Ferrocenylethylamine.AUSTRALIAN JOURNAL OF CHEMISTRY,66(2),218-226. |
| MLA | Yin, Zhigang,et al."Electrochemical Properties and Regioselectivity of Cyclopalladation of Chiral Ferrocenylimines Deriving from (S)-Ferrocenylethylamine".AUSTRALIAN JOURNAL OF CHEMISTRY 66.2(2013):218-226. |
入库方式： OAI收割
来源：青岛生物能源与过程研究所
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