Synthesis and Characterization of Functional Thienyl-Phosphine Microporous Polymers for Carbon Dioxide Capture
文献类型：期刊论文
| 作者 | Chen, Xianghui1,2; Qiao, Shanlin1; Du, Zhengkun1; Zhou, Yuanhang1; Yang, Renqiang1
|
| 刊名 | MACROMOLECULAR RAPID COMMUNICATIONS
 |
| 出版日期 | 2013-07-25 |
| 卷号 | 34期号:14页码:1181-1185 |
| 关键词 | functionalization of polymers gas capture property heat capacity thienyl-phosphine networks |
| 英文摘要 | A novel kind of functional organic microporous polymer is designed by introducing polar organic groups (P=O and P=S) and electron-rich heterocyclic into the framework to obtain high carbon dioxide capture capacity. The estimated Brunauer-Emmett-Teller (BET) surface areas of these polymers are about 600 m(2) g(-1) and the highest CO2 uptake is 2.26 mmol g(-1) (1.0 bar/273 K). Interestingly, the polymer containing P=O groups shows greater CO2 capture capacity than that containing P=S groups at the same temperature. In addition, these polymers show high isosteric heats of CO2 adsorption (28.6 kJ mol(-1)), which can be competitive with some nitrogen-rich networks. Therefore, these microporous polymers are promising candidates for carbon dioxide capture. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 学科主题 | 先进功能有机材料 |
| 类目[WOS] | Polymer Science |
| 研究领域[WOS] | Polymer Science |
| 关键词[WOS] | HIGH-SURFACE-AREA ; METAL-ORGANIC FRAMEWORK ; GAS-STORAGE ; CO2 ; SEPARATION ; NETWORKS ; SIMULATION ; COPOLYMER ; POROSITY |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000325870200010 |
| 公开日期 | 2014-03-25 |
| 源URL | [http://ir.qibebt.ac.cn:8080/handle/337004/1702]  |
| 专题 | 青岛生物能源与过程研究所_先进有机功能材料团队 |
| 作者单位 | 1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chen, Xianghui,Qiao, Shanlin,Du, Zhengkun,et al. Synthesis and Characterization of Functional Thienyl-Phosphine Microporous Polymers for Carbon Dioxide Capture[J]. MACROMOLECULAR RAPID COMMUNICATIONS,2013,34(14):1181-1185. |
| APA | Chen, Xianghui,Qiao, Shanlin,Du, Zhengkun,Zhou, Yuanhang,&Yang, Renqiang.(2013).Synthesis and Characterization of Functional Thienyl-Phosphine Microporous Polymers for Carbon Dioxide Capture.MACROMOLECULAR RAPID COMMUNICATIONS,34(14),1181-1185. |
| MLA | Chen, Xianghui,et al."Synthesis and Characterization of Functional Thienyl-Phosphine Microporous Polymers for Carbon Dioxide Capture".MACROMOLECULAR RAPID COMMUNICATIONS 34.14(2013):1181-1185. |
入库方式： OAI收割
来源：青岛生物能源与过程研究所
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