Gasification kinetic analysis of the three pseudocomponents of biomass-cellulose, semicellulose and lignin
文献类型:期刊论文
作者 | Chen, Tianju1![]() ![]() ![]() ![]() |
刊名 | BIORESOURCE TECHNOLOGY
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出版日期 | 2014-02-01 |
卷号 | 153期号:153c页码:223-229 |
关键词 | Gasification Kinetic analysis Pseudocomponent Biomass |
中文摘要 | The gasification kinetic analysis of the three pseudocomponents (hemicellulose, cellulose and lignin) of biomass decomposition in the agent of CO2 were investigated. The Multi-peaks method was used to fit the Gaussian distribution model of DTG curves. The Friedman method was used to estimate the effective Ea, and the master plot method was used for the determination of the kinetic model. The results showed that there were two reaction stages for semi-cellulose and lignin. The DTG curves of semicellulose and lignin cannot be fitted by Gaussian distribution model. The Ea were ranged from 80 to 220 kJ mol_1 for the three pseudocomponents. The Fn model could describe the kinetic process of stage I of semi-cellulose decomposition. Both cellulose and stage II of semicellulose decomposition could be described by An model and the two reaction stages of the lignin were fitted the Rn model very well |
英文摘要 | The gasification kinetic analysis of the three pseudocomponents (hemicellulose, cellulose and lignin) of biomass decomposition in the agent of CO2 were investigated. The Multi-peaks method was used to fit the Gaussian distribution model of DTG curves. The Friedman method was used to estimate the effective E alpha, and the master plot method was used for the determination of the kinetic model. The results showed that there were two reaction stages for semi-cellulose and lignin. The DTG curves of semicellulose and lignin cannot be fitted by Gaussian distribution model. The E-alpha were ranged from 80 to 220 kJ mol (1) for the three pseudocomponents. The F-n model could describe the kinetic process of stage I of semi-cellulose decomposition. Both cellulose and stage II of semicellulose decomposition could be described by A(n) model and the two reaction stages of the lignin were fitted the R-n model very well. (C) 2013 Elsevier Ltd. All rights reserved. |
WOS标题词 | Science & Technology ; Life Sciences & Biomedicine ; Technology |
学科主题 | 热化学转化 |
类目[WOS] | Agricultural Engineering ; Biotechnology & Applied Microbiology ; Energy & Fuels |
研究领域[WOS] | Agriculture ; Biotechnology & Applied Microbiology ; Energy & Fuels |
关键词[WOS] | ACTIVATION-ENERGY ; STRAW PYROLYSIS ; CHINA ; MODEL ; CO2 |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000331461000030 |
公开日期 | 2014-03-21 |
源URL | [http://ir.qibebt.ac.cn:8080/handle/337004/1597] ![]() |
专题 | 青岛生物能源与过程研究所_热化学转化事业部 |
作者单位 | 1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Key Lab Biofuels, Qingdao 266101, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Chen, Tianju,Wu, Jingli,Zhang, Jinzhi,et al. Gasification kinetic analysis of the three pseudocomponents of biomass-cellulose, semicellulose and lignin[J]. BIORESOURCE TECHNOLOGY,2014,153(153c):223-229. |
APA | Chen, Tianju,Wu, Jingli,Zhang, Jinzhi,Wu, Jinhu,&Sun, Li.(2014).Gasification kinetic analysis of the three pseudocomponents of biomass-cellulose, semicellulose and lignin.BIORESOURCE TECHNOLOGY,153(153c),223-229. |
MLA | Chen, Tianju,et al."Gasification kinetic analysis of the three pseudocomponents of biomass-cellulose, semicellulose and lignin".BIORESOURCE TECHNOLOGY 153.153c(2014):223-229. |
入库方式: OAI收割
来源:青岛生物能源与过程研究所
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