Hydrogenolysis of biomass-derived sorbitol to glycols and glycerol over Ni-MgO catalysts.
文献类型：期刊论文
| 作者 | Chen, X. ; Wang, X. ; Yao, S. ; & Mu, X. |
| 刊名 | Catalysis Communications
 |
| 出版日期 | 2013 |
| 期号 | 39页码:86-89 |
| 关键词 | Sorbitol Hydrogenolysis Glycols Ni-MgO Basic carrier |
| 中文摘要 | Ni-MgO catalysts with varying Ni/Mg ratios were prepared by co-precipitation and tested in sorbitol hydrogenolysis. At 473 K and 4 MPa H2, the best catalyst with Ni/Mg ratio of 3:7 exhibited 67.8% conversion and 80.8% total selectivity of ethylene glycol, 1,2-propylene glycol and glycerol. These catalysts were characterized by XRD, CO2-TPD and H2 chemisorption, revealing that the activity depended strongly on the basicity and Ni surface area. The reaction conditions were optimized, which were relatively mild for this chemoselective conversion. |
| 学科主题 | 绿色化学催化 |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2014-03-21 |
| 源URL | [http://ir.qibebt.ac.cn:8080/handle/337004/1652]  |
| 专题 | 青岛生物能源与过程研究所_绿色化学催化团队 |
| 推荐引用方式 GB/T 7714 | Chen, X.,Wang, X.,Yao, S.,et al. Hydrogenolysis of biomass-derived sorbitol to glycols and glycerol over Ni-MgO catalysts.[J]. Catalysis Communications,2013(39):86-89. |
| APA | Chen, X.,Wang, X.,Yao, S.,&& Mu, X..(2013).Hydrogenolysis of biomass-derived sorbitol to glycols and glycerol over Ni-MgO catalysts..Catalysis Communications(39),86-89. |
| MLA | Chen, X.,et al."Hydrogenolysis of biomass-derived sorbitol to glycols and glycerol over Ni-MgO catalysts.".Catalysis Communications .39(2013):86-89. |
入库方式： OAI收割
来源：青岛生物能源与过程研究所
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