Binuclear zirconium complexes with bidentate N-(ortho-dimethylaminobenzyl)anilide ligands: Synthesis, characterization, and catalytic properties for ethylene polymerization and copolymerization with 1-hexene.
文献类型：期刊论文
| 作者 | Liu, K. ; Wu, Q. ; Mu, X. ; Gao, W. ; & Mu, Y. |
| 刊名 | Polyhedron
 |
| 出版日期 | 2013 |
| 期号 | 52页码:222-226 |
| 关键词 | Ethylene polymerization Olefin polymerization Polyethylene Zirconium complexes |
| 中文摘要 | A series of binuclear zirconium complexes of the type [ortho-(Me2N)C6H4CH2NArZrCl2(l-Cl)]2 [Ar = 2,6-Me2C6H3 (1), 2,6-Et2C6H3 (2), 2,6-iPr2C6H3 (3)] were synthesized by reactions of ZrCl4 with corresponding ortho-(Me2N)C6H4CH2NArLi. All new zirconium complexes were characterized by 1H and 13C NMR spectroscopy and elemental analyses. The molecular structures of complexes 1 and 2 were determined by single crystal X-ray diffraction analysis. Upon activation with AliBu3 and Ph3CB(C6F5)4, complexes 1–3 exhibit moderate catalytic activity for ethylene polymerization and copolymerization with 1-hexene, producing high or ultra high molecular weight polyethylene or relatively high molecular weight poly (ethylene-co-1-hexene) with reasonable 1-hexene incorporation. |
| 学科主题 | 绿色化学催化 |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2014-03-24 |
| 源URL | [http://ir.qibebt.ac.cn:8080/handle/337004/1662]  |
| 专题 | 青岛生物能源与过程研究所_绿色化学催化团队 |
| 推荐引用方式 GB/T 7714 | Liu, K.,Wu, Q.,Mu, X.,et al. Binuclear zirconium complexes with bidentate N-(ortho-dimethylaminobenzyl)anilide ligands: Synthesis, characterization, and catalytic properties for ethylene polymerization and copolymerization with 1-hexene.[J]. Polyhedron,2013(52):222-226. |
| APA | Liu, K.,Wu, Q.,Mu, X.,Gao, W.,&& Mu, Y..(2013).Binuclear zirconium complexes with bidentate N-(ortho-dimethylaminobenzyl)anilide ligands: Synthesis, characterization, and catalytic properties for ethylene polymerization and copolymerization with 1-hexene..Polyhedron(52),222-226. |
| MLA | Liu, K.,et al."Binuclear zirconium complexes with bidentate N-(ortho-dimethylaminobenzyl)anilide ligands: Synthesis, characterization, and catalytic properties for ethylene polymerization and copolymerization with 1-hexene.".Polyhedron .52(2013):222-226. |
入库方式： OAI收割
来源：青岛生物能源与过程研究所
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