Phosphotungstic acid-assisted preparation of carbon nanotubes-supported uniform Pt and Pt bimetallic nanoparticles, and their enhanced catalytic activity on methanol electro-oxidation
文献类型：期刊论文
| 作者 | Lu J ; Hong LJ ; Yang YY ; Xu SJ ; Wang S ; Yuan JH ; Niu L |
| 刊名 | journal of nanoparticle research
 |
| 出版日期 | 2013 |
| 卷号 | 16期号:1页码:文献号:unsp 2162 |
| 关键词 | FUEL-CELL DMFC PORTABLE APPLICATIONS POLYOXOMETALATE OXIDATION ELECTROCATALYST FUNCTIONALIZATION PERFORMANCE |
| ISSN号 | 1388-0764 |
| 通讯作者 | yuan jh |
| 中文摘要 | a 3-4 nm thickness of phosphotungstic acid (h3pw12o40, pw) layer is deposited on to the surface of multiwalled carbon nanotubes (mwcnts) via sorption by ultrasonic method. these pw/mwcnt hybrids can be used as the promising supports for anode catalysts of the direct methanol fuel cell (dmfc). a facile polyol thermo-reduction method has been put forward to prepare ptir (ptru or pt)/pw/mwcnt hybrids. in the presence of pw, ptir (ptru or pt) nanoparticles can be uniformly dispersed on the surface of the mwcnts in high density with a small size and a narrow distribution, and these pt and pt bimetallic catalysts exhibit a significantly improved electrochemically active surface area and a remarkably enhanced activity toward methanol oxidation. besides, these pt and pt bimetallic catalysts on pw/mwcnt hybrids also show longer operation stability and higher co tolerance as well as better cell performance compared with those on mwcnts without pw. the evaluation of anode catalysts in dmfc indicates that the observed power density depends on the intrinsic property of the size, dispersion and composition of pt and pt bimetallic catalysts. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000328224300001 |
| 公开日期 | 2014-04-14 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/49407]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Lu J,Hong LJ,Yang YY,et al. Phosphotungstic acid-assisted preparation of carbon nanotubes-supported uniform Pt and Pt bimetallic nanoparticles, and their enhanced catalytic activity on methanol electro-oxidation[J]. journal of nanoparticle research,2013,16(1):文献号:unsp 2162. |
| APA | Lu J.,Hong LJ.,Yang YY.,Xu SJ.,Wang S.,...&Niu L.(2013).Phosphotungstic acid-assisted preparation of carbon nanotubes-supported uniform Pt and Pt bimetallic nanoparticles, and their enhanced catalytic activity on methanol electro-oxidation.journal of nanoparticle research,16(1),文献号:unsp 2162. |
| MLA | Lu J,et al."Phosphotungstic acid-assisted preparation of carbon nanotubes-supported uniform Pt and Pt bimetallic nanoparticles, and their enhanced catalytic activity on methanol electro-oxidation".journal of nanoparticle research 16.1(2013):文献号:unsp 2162. |
入库方式： OAI收割
来源：长春应用化学研究所
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