Determination of ultra-low glass transition temperature via differential scanning calorimetry
文献类型：期刊论文
| 作者 | Feng LD ; Bian XC ; Li G ; Chen ZM ; Cui Y ; Chen XS |
| 刊名 | polymer testing
 |
| 出版日期 | 2013 |
| 卷号 | 32期号:8页码:1368-1372 |
| 关键词 | INVERSE GAS-CHROMATOGRAPHY POLY(ETHYLENE GLYCOL) POLYMERS |
| ISSN号 | 0142-9418 |
| 通讯作者 | chen xs |
| 中文摘要 | a novel method was developed to determine the ultra-low glass transition temperature (t-g) of materials through physical blending via differential scanning calorimetry. according to the fox equation for polymer blends, a blend of two fully compatible polymers has only one t-g. the single t-g is a function of the t(g)s of the two simple polymers. thus, the ultra-low t-g of one material can be obtained from the t(g)s of another polymer and their blends. the error of t-g measurements depends on the measurement error of the t(g)s for the blends and another polymer. the method was successfully applied to determine the t(g)s of acetyl tributyl citrate (atbc), tributyl citrate (tbc) and poly(ethylene glycol)s (peg)s with different molecular weights. the t(g)s for atbc, tbc, peg-4000 and peg-800 were -57.0 degrees c, -62.7 degrees c, -76.6 degrees c and -83.1 degrees c, respectively. for all the samples, the standard deviation of measurements was less than 3.3 degrees c, and the absolute error of measurements was theoretically not more than 5.3 degrees c. these results indicate that this method has acceptable precision and accuracy. (c) 2013 elsevier ltd. all rights reserved. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000329143700011 |
| 公开日期 | 2014-04-15 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/49419]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Feng LD,Bian XC,Li G,et al. Determination of ultra-low glass transition temperature via differential scanning calorimetry[J]. polymer testing,2013,32(8):1368-1372. |
| APA | Feng LD,Bian XC,Li G,Chen ZM,Cui Y,&Chen XS.(2013).Determination of ultra-low glass transition temperature via differential scanning calorimetry.polymer testing,32(8),1368-1372. |
| MLA | Feng LD,et al."Determination of ultra-low glass transition temperature via differential scanning calorimetry".polymer testing 32.8(2013):1368-1372. |
入库方式： OAI收割
来源：长春应用化学研究所
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