Synthesis and characterization of novel sulfonated polyimides from 4,6-bis(4-aminophenoxy)-naphthalene-2-sulfonic acid
文献类型：期刊论文
| 作者 | Li YH ; Wang WJ ; Jin RZ ; Gao LX |
| 刊名 | chemical research in chinese universities
 |
| 出版日期 | 2013 |
| 卷号 | 29期号:6页码:1225-1228 |
| 关键词 | PROTON-EXCHANGE MEMBRANES FUEL-CELL APPLICATION POLYELECTROLYTES CONDUCTIVITY STABILITY |
| ISSN号 | 1005-9040 |
| 通讯作者 | gao lx |
| 中文摘要 | a novel sulfonated diamine monomer, 4,6-bis(4-aminophenoxy)-naphthalene-2-sulfonic acid(bapns), was synthesized. a series of sulfonated polyimide copolymers was prepared from bapns, 1,4,5,8-naphthalenetetra-carboxylic dianhydride(ntda) and nonsulfonated diamine 4,4'-diaminodiphenyl ether(oda). flexible, transparent, and mechanically strong membranes were obtained. the novel sulfonated polyimide(spi) membranes show higher conductivity, for example, spi-100 shows a conductivity of 0.0698 s/cm at 80 a degrees c(spi-x: x refers to molar fraction of bapns). the membranes exhibit the permeability of methanol from 2.18x10(-7) cm(2)/s to 2.57x10(-7) cm(2)/s, which is much lower than that of nafion(2.00x10(-6) cm(2)/s). the copolymers were thermally stable up to 330 a degrees c. the sulfonated polyimide copolymers also show reasonable mechanical strength; for example, the maximum tensile strength at break of the sulfonated polyimide copolymer with 100%(molar fraction) bapns is 1.35 gpa under high moisture conditions. the optimum concentration of bapns was found to be 100%(molar fraction) from the view point of proton conductivity, methanol permeability, and membrane stability. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000329095200040 |
| 公开日期 | 2014-04-15 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/49421]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Li YH,Wang WJ,Jin RZ,et al. Synthesis and characterization of novel sulfonated polyimides from 4,6-bis(4-aminophenoxy)-naphthalene-2-sulfonic acid[J]. chemical research in chinese universities,2013,29(6):1225-1228. |
| APA | Li YH,Wang WJ,Jin RZ,&Gao LX.(2013).Synthesis and characterization of novel sulfonated polyimides from 4,6-bis(4-aminophenoxy)-naphthalene-2-sulfonic acid.chemical research in chinese universities,29(6),1225-1228. |
| MLA | Li YH,et al."Synthesis and characterization of novel sulfonated polyimides from 4,6-bis(4-aminophenoxy)-naphthalene-2-sulfonic acid".chemical research in chinese universities 29.6(2013):1225-1228. |
入库方式： OAI收割
来源：长春应用化学研究所
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