Efficient blue and bluish-green iridium phosphors: Fine-tuning emissions of FIrpic by halogen substitution on pyridine-containing ligands
文献类型：期刊论文
| 作者 | Fan C ; Zhu LP ; Jiang B ; Zhong C ; Ma DG ; Qin JG ; Yang CL |
| 刊名 | organic electronics
 |
| 出版日期 | 2013 |
| 卷号 | 14期号:12页码:3163-3171 |
| 关键词 | LIGHT-EMITTING-DIODES ORGANIC ELECTROLUMINESCENT DEVICES HOST MATERIALS COMPLEXES OLEDS PHOTOPHYSICS EMITTERS |
| ISSN号 | 1566-1199 |
| 通讯作者 | ma dg |
| 中文摘要 | three new iridium compounds, 4-f-firpic, 4-cl-firpic and 4-br-firpic, were designed and synthesized by introducing the f, cl and br atoms to the 4-position of pyridine ring in the frame of sky-blue emitter, firpic. adding f atom stabilizes the homo level of firpic but keeps the lumo level of firpic almost unchanged, which consequently broadens the homo-lumo gap of firpic and finely tunes the emission to 465 nm of 4-f-firpic from 470 nm of firpic. in contrast, introducing of cl and br atoms simultaneously lowers the homo and lumo levels of firpic, which brings about the squeeze of homo-lumo gap in firpic and makes the emissions of 4-cl-firpic and 4-br-firpic red-shift to 475 and 479 nm, respectively. the phosphorescent organic light-emitting devices using the three iridium compounds as dopants were fabricated with the following configuration: ito/moo3/tapc/tcta: dopants/tm/lif/al. the device based on 4-f-firpic showed a blue emission with the commission internationale de l'eclairage coordinate of (0.15, 0.28), and revealed rather high efficiencies, with maximum current efficiency of 29 cd a(-1), power efficiency of 29 lm w-1 and external quantum efficiency of 14.6%. (c) 2013 elsevier b.v. all rights reserved. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000327146500003 |
| 公开日期 | 2014-04-15 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/49436]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Fan C,Zhu LP,Jiang B,et al. Efficient blue and bluish-green iridium phosphors: Fine-tuning emissions of FIrpic by halogen substitution on pyridine-containing ligands[J]. organic electronics,2013,14(12):3163-3171. |
| APA | Fan C.,Zhu LP.,Jiang B.,Zhong C.,Ma DG.,...&Yang CL.(2013).Efficient blue and bluish-green iridium phosphors: Fine-tuning emissions of FIrpic by halogen substitution on pyridine-containing ligands.organic electronics,14(12),3163-3171. |
| MLA | Fan C,et al."Efficient blue and bluish-green iridium phosphors: Fine-tuning emissions of FIrpic by halogen substitution on pyridine-containing ligands".organic electronics 14.12(2013):3163-3171. |
入库方式： OAI收割
来源：长春应用化学研究所
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