Hopper-like framework growth evolution in a cubic system: a case study of Cu2O
文献类型：期刊论文
| 作者 | Chen KF ; Song SY ; Xue DF |
| 刊名 | journal of applied crystallography
 |
| 出版日期 | 2013 |
| 卷号 | 46页码:1603-1609 |
| 关键词 | CUPROUS-OXIDE CRYSTAL-GROWTH LIQUID-PHASE NANOCRYSTALS COPPER CITRATE CRYSTALLIZATION NANOSTRUCTURES MORPHOLOGY CHEMISTRY |
| ISSN号 | 0021-8898 |
| 通讯作者 | xue df |
| 中文摘要 | crystallization of hopper-like cu2o cubes is demonstrated in alkaline citrate-copper solution upon the equilibrium between complexation, precipitation and redox reactions. the complexation reactions of na(3)cit and naoh with cu2+ manipulate the current chemical reaction routes, phase transformation, and thus crystallization morphologies and compositions. during the crystallization of cu2o variations of mother solution such as ph and the concentration of cu2+ (cu+) are monitored by ex situ ph measurement and uv-vis absorption spectroscopy. the shape evolution of cu2o hopper cubes is consistent with the chemical reaction routes, which demonstrates the interplay between chemical reactions and crystal growth. the appropriate reaction concentration, na(3)cit:cu2+ > 2 and 1 < naoh:cu2+ < 2, has been identified for the growth of these hopper cubes. the current reaction-controllable crystal growth may further the synthesis chemistry toward rational control over crystallization. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000327070000010 |
| 公开日期 | 2014-04-15 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/49438]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Chen KF,Song SY,Xue DF. Hopper-like framework growth evolution in a cubic system: a case study of Cu2O[J]. journal of applied crystallography,2013,46:1603-1609. |
| APA | Chen KF,Song SY,&Xue DF.(2013).Hopper-like framework growth evolution in a cubic system: a case study of Cu2O.journal of applied crystallography,46,1603-1609. |
| MLA | Chen KF,et al."Hopper-like framework growth evolution in a cubic system: a case study of Cu2O".journal of applied crystallography 46(2013):1603-1609. |
入库方式： OAI收割
来源：长春应用化学研究所
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