Synthesis and characterization of random or gradient butadiene-p-methylstyrene copolymers via anionic polymerization
文献类型：期刊论文
| 作者 | Liu F ; Tan HY ; Tang T |
| 刊名 | chinese journal of polymer science
 |
| 出版日期 | 2013 |
| 卷号 | 31期号:12页码:1647-1659 |
| 关键词 | BLOCK-COPOLYMERS LIVING POLYMERIZATION STYRENE COPOLYMERS GRAFT-COPOLYMERS ISOPRENE POLYETHYLENE METALLOCENE HYDROGENATION POLYSTYRENE CATALYSTS |
| ISSN号 | 0256-7679 |
| 通讯作者 | tang t |
| 中文摘要 | copolymers of 1,3-butadiene and p-methylstyrene (p-ms) were synthesized via anionic polymerization. a benzophenone-potassium complex was added to tune the reactivity ratio of the two monomers, leading to random and gradient composition along the copolymer chain. the overall composition and microstructure could be controlled and well characterized by gpc and h-1-nmr. the p-ms was distributed from gradient to random with increasing the content of the benzophenone-potassium complex, and the 1,2-microstructure in the polybutadiene sequence increased at the same time. the hydrogenation of the copolymer of 1,3-butadiene and p-ms resulted in the corresponding saturated copolymer with welldefined structure and narrow molecular weight distribution. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000326884900005 |
| 公开日期 | 2014-04-15 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/49441]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Liu F,Tan HY,Tang T. Synthesis and characterization of random or gradient butadiene-p-methylstyrene copolymers via anionic polymerization[J]. chinese journal of polymer science,2013,31(12):1647-1659. |
| APA | Liu F,Tan HY,&Tang T.(2013).Synthesis and characterization of random or gradient butadiene-p-methylstyrene copolymers via anionic polymerization.chinese journal of polymer science,31(12),1647-1659. |
| MLA | Liu F,et al."Synthesis and characterization of random or gradient butadiene-p-methylstyrene copolymers via anionic polymerization".chinese journal of polymer science 31.12(2013):1647-1659. |
入库方式： OAI收割
来源：长春应用化学研究所
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