Methoxy-Directed Aryl-to-Aryl 1,3-Rhodium Migration
文献类型：期刊论文
| 作者 | Zhang J ; Liu JF ; Ugrinov A ; Pillai AFX ; Sun ZM ; Zhao PJ |
| 刊名 | journal of the american chemical society
 |
| 出版日期 | 2013 |
| 卷号 | 135期号:46页码:17270-17273 |
| 关键词 | C-H ACTIVATION CROSS-COUPLING REACTIONS BOND ACTIVATION PALLADIUM MIGRATION RHODIUM ACIDS HECK COMPLEXES CYCLOCARBOPALLADATION FUNCTIONALIZATION |
| ISSN号 | 0002-7863 |
| 通讯作者 | sun zm |
| 中文摘要 | through-space metal/hydrogen shift is an important strategy for transition-metal-catalyzed c-h bond activation. here we describe the synthesis and characterization of a rh(i) 2,6-dimethoxybenzoate complex that underwent stoichiometric rearrangement via a highly unusual 1,3-rhodium migration. this aryl-to-aryl 1,3-rh/h shift was also demonstrated in a rh(i)-catalyzed decarboxylative conjugate addition to form a c-c bond at a meta position instead of the ipso-carboxyl position. a deuterium-labeling study under the conditions of rh(i)-catalyzed protodecarboxylation revealed the involvement of an ortho-methoxy group in a multistep pathway of consecutive sp(3) and sp(2) c-h bond activations. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000327413300009 |
| 公开日期 | 2014-04-15 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/49456]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Zhang J,Liu JF,Ugrinov A,et al. Methoxy-Directed Aryl-to-Aryl 1,3-Rhodium Migration[J]. journal of the american chemical society,2013,135(46):17270-17273. |
| APA | Zhang J,Liu JF,Ugrinov A,Pillai AFX,Sun ZM,&Zhao PJ.(2013).Methoxy-Directed Aryl-to-Aryl 1,3-Rhodium Migration.journal of the american chemical society,135(46),17270-17273. |
| MLA | Zhang J,et al."Methoxy-Directed Aryl-to-Aryl 1,3-Rhodium Migration".journal of the american chemical society 135.46(2013):17270-17273. |
入库方式： OAI收割
来源：长春应用化学研究所
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