Effect of Ce on electrochemical properties of the TiVNi quasicrystal material as an anode for Ni/MH batteries
文献类型：期刊论文
| 作者 | Liu WQ ; Duan Q ; Liang F ; Lin J ; Jiang DY ; Wang LM |
| 刊名 | international journal of hydrogen energy
 |
| 出版日期 | 2013 |
| 卷号 | 38期号:34页码:14810-14815 |
| ISSN号 | 0360-3199 |
| 关键词 | HYDROGEN STORAGE Y ALLOYS ELECTRODE MICROSTRUCTURE DIFFRACTION POWDERS RE |
| 通讯作者 | liu wq |
| 中文摘要 | in order to investigate effect of ce on electrochemical properties of the ti1.4v/ni-0.6 quasi-crystal, (ti1.4v0.6ni)(99.4)ce-0.6 alloy ribbon is prepared by arc melting and subsequent melt-spinning technique. the electrochemical properties of the ti1.4v0.6ni and (ti1.4v0.6ni)(99.4)ce-0.6 are studied as negative electrode for nickel-metal hydride batteries in aqueous koh solution. the structures of the alloys were characterized by xrd and tem. phase structure investigations of the (ti1.4v0.6ni)(99) ce-4(0.6) show that alloy mainly consist of the icosahedral quasicrystal (i-phase) and face centered cubic (fcc) phase with ti2ni-type structure. the electrochemical measurements demonstrated that the negative electrode made by (ti1.4v0.6ni)(99.4)ce-0.6 alloy showed an improved electrochemical reversibility and a considerably higher charge-discharge capacity when compared to the ce-free base alloy. its maximum discharge capacity is about 300 mah/g, which is higher than that of ti1.4v0.6ni, and remains 270 mah/g after 30 cycles at a current density of 30 ma/g. the discharge process is also characterized by electrochemical impedance spectroscopy. copyright (c) 2013, hydrogen energy publications, llc. published by elsevier ltd. all rights reserved. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000328517700044 |
| 公开日期 | 2014-04-15 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/49479]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Liu WQ,Duan Q,Liang F,et al. Effect of Ce on electrochemical properties of the TiVNi quasicrystal material as an anode for Ni/MH batteries[J]. international journal of hydrogen energy,2013,38(34):14810-14815. |
| APA | Liu WQ,Duan Q,Liang F,Lin J,Jiang DY,&Wang LM.(2013).Effect of Ce on electrochemical properties of the TiVNi quasicrystal material as an anode for Ni/MH batteries.international journal of hydrogen energy,38(34),14810-14815. |
| MLA | Liu WQ,et al."Effect of Ce on electrochemical properties of the TiVNi quasicrystal material as an anode for Ni/MH batteries".international journal of hydrogen energy 38.34(2013):14810-14815. |
入库方式： OAI收割
来源：长春应用化学研究所
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