Core Cross-Linked Micelle-Based Nanoreactors for Efficient Photocatalysis
文献类型：期刊论文
| 作者 | Zheng M ; Sun ZC ; Xie ZG ; Jing XB |
| 刊名 | chemistry-an asian journal
 |
| 出版日期 | 2013 |
| 卷号 | 8期号:11页码:2807-2812 |
| 关键词 | BLOCK-COPOLYMER MICELLES SELF-ASSEMBLED NANOREACTORS VISIBLE-LIGHT RESPONSIVE VESICLES FACILE SYNTHESIS DRUG-DELIVERY OXIDATION SULFOXIDES COMPLEXES POLYMERS |
| ISSN号 | 1861-4728 |
| 通讯作者 | sun zc |
| 中文摘要 | stable nanoscale cross-linked polymer micelles containing ru complexes (ru-cms) were prepared from monomethoxy[poly(ethylene glycol)]-block-poly(l-lysine) (mpeg-plys) and [(bpy)(2)ru(fmbpy)](pf6)(2) (bpy=bipyridine, fmbpy=5-formy-5-methyl-2,2-bipyridine). to stabilize the micelles, bifunctional glutaraldehyde was used as a cross-linker to react with the free amino groups of the plys block. after that, the ru-cms showed very good stability in common solvents. the ru-cms showed photocatalytic activity and selectivity in the oxidation of sulfides that were as high as those of the well-known [ru(bpy)(3)(pf6)(2)] complex, because the micelles were swollen in the methanol-sulfide mixture. moreover, because of the nanoscale size of the particles and their high stability, the ru-cm photocatalysts can be readily recovered by ultrafiltration and reused without loss of photocatalytic activity. this work highlights the potential of using cross-linked micelles as a platform for developing highly efficient heterogeneous photocatalysts for a number of important organic transformations. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000326292200043 |
| 公开日期 | 2014-04-15 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/49503]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Zheng M,Sun ZC,Xie ZG,et al. Core Cross-Linked Micelle-Based Nanoreactors for Efficient Photocatalysis[J]. chemistry-an asian journal,2013,8(11):2807-2812. |
| APA | Zheng M,Sun ZC,Xie ZG,&Jing XB.(2013).Core Cross-Linked Micelle-Based Nanoreactors for Efficient Photocatalysis.chemistry-an asian journal,8(11),2807-2812. |
| MLA | Zheng M,et al."Core Cross-Linked Micelle-Based Nanoreactors for Efficient Photocatalysis".chemistry-an asian journal 8.11(2013):2807-2812. |
入库方式： OAI收割
来源：长春应用化学研究所
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