Synthesis and structural characterization of magnesium complexes bearing phenanthrene imine derivative ligands
文献类型：期刊论文
| 作者 | Gao B ; Xin L ; Gao W ; Hao ZQ ; Xin XZ ; Wu QL ; Mu Y |
| 刊名 | polyhedron
 |
| 出版日期 | 2013 |
| 卷号 | 63页码:91-95 |
| 关键词 | BIDENTATE NITROGEN LIGANDS ORGANOMETALLIC CHEMISTRY HOMOGENEOUS CATALYSIS MOLECULAR-STRUCTURE (ALPHA-DIIMINE)NICKEL(II) CATALYSTS CHROMIUM COMPLEXES CALCIUM COMPLEXES POLYMERIZATION PALLADIUM CRYSTAL |
| ISSN号 | 0277-5387 |
| 通讯作者 | gao w |
| 中文摘要 | reduction reactions of the phenanthrene-o-aryliminoquinone with 0.5 equiv of magnesium in tetrahydrofuran afford the bisligated magnesium complexes [(ar)piq](2)mg(thf) (1a, ar = 2,6-me2c6h3; 1b, ar = 2,6-(pr2c6h3)-pr-i). 1a can be further reduced by magnesium to oxygen-bridged dinuclear complex [(mu-o)(ar-)piqmg(thf)(2)](2) (2). similar reduction reactions of the n,n-bis(arylimino)phenanthrene with magnesium give bis(arylimino)phenanthrene magnesium complexes (ar1,ar2)bipmg(thf)(3) (3, ar-1 = ar-2 = 2,6-me2c6h3: 4, ar-1 = ar-2 = 2,6-(pr2c6h3)-pr-i: 5, ar-1 = 2,6-me2c6h3, ar-2 = 2,6-(pr2c6h3)-pr-i). all the complexes were well characterized and the molecular structures of 1b, 2, 3, and 5 were established by x-ray diffraction analysis. (c) 2013 elsevier ltd. all rights reserved. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000324849200014 |
| 公开日期 | 2014-04-15 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/49523]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Gao B,Xin L,Gao W,et al. Synthesis and structural characterization of magnesium complexes bearing phenanthrene imine derivative ligands[J]. polyhedron,2013,63:91-95. |
| APA | Gao B.,Xin L.,Gao W.,Hao ZQ.,Xin XZ.,...&Mu Y.(2013).Synthesis and structural characterization of magnesium complexes bearing phenanthrene imine derivative ligands.polyhedron,63,91-95. |
| MLA | Gao B,et al."Synthesis and structural characterization of magnesium complexes bearing phenanthrene imine derivative ligands".polyhedron 63(2013):91-95. |
入库方式： OAI收割
来源：长春应用化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。