Micellization of St/MMA Gradient Copolymers: A General Picture of Structural Transitions in Gradient Copolymer Micelles
文献类型：期刊论文
| 作者 | Zheng C ; Huang HY ; He TB |
| 刊名 | macromolecular rapid communications
 |
| 出版日期 | 2013 |
| 卷号 | 34期号:20页码:1654-1661 |
| 关键词 | CRITICAL SOLUTION TEMPERATURE BLOCK-COPOLYMERS AQUEOUS-SOLUTIONS INTEGRAL-EQUATIONS DRUG-DELIVERY POLYMERIZATION METHACRYLATE BEHAVIOR DESIGN MEDIA |
| ISSN号 | 1022-1336 |
| 通讯作者 | huang hy |
| 中文摘要 | in this work, a gradient copolymer of styrene (st) and methyl methacrylate (mma) is synthesized via reversible addition-fragmentation chain transfer living radical polymerization and its micellization behaviors in an acetone and water mixture are investigated by transmission electron microscopy, light scattering, and nmr spectroscopy. three different kinds of transitions were found to coexist in a single system for the first time: a unimers to micelles transition, a star-like micelles to crew-cut micelles transition resulting from the shrinkage of micelles, and morphological transitions from spherical micelles to cylindrical micelles to vesicles. our findings provide a general picture of structural transitions and relaxation processes in gradient copolymer micelles, which can lead to the development of novel materials and applications based on gradient copolymers. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000325610000010 |
| 公开日期 | 2014-04-15 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/49568]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Zheng C,Huang HY,He TB. Micellization of St/MMA Gradient Copolymers: A General Picture of Structural Transitions in Gradient Copolymer Micelles[J]. macromolecular rapid communications,2013,34(20):1654-1661. |
| APA | Zheng C,Huang HY,&He TB.(2013).Micellization of St/MMA Gradient Copolymers: A General Picture of Structural Transitions in Gradient Copolymer Micelles.macromolecular rapid communications,34(20),1654-1661. |
| MLA | Zheng C,et al."Micellization of St/MMA Gradient Copolymers: A General Picture of Structural Transitions in Gradient Copolymer Micelles".macromolecular rapid communications 34.20(2013):1654-1661. |
入库方式： OAI收割
来源：长春应用化学研究所
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