Synthesis of monodisperse, large scale and high solid content latexes of poly(n-butyl acrylate) by a one-step batch emulsion polymerization
文献类型：期刊论文
| 作者 | Liu BJ ; Zhang MY ; Zhou C ; Ren L ; Cheng HL ; Ao YH ; Zhang HX |
| 刊名 | colloid and polymer science
 |
| 出版日期 | 2013 |
| 卷号 | 291期号:10页码:2385-2398 |
| 关键词 | SODIUM DODECYL-SULFATE MONOMER-STARVED CONDITIONS PARTICLE FORMATION BUTYL ACRYLATE POLY(BUTYLENE TEREPHTHALATE) COAGULATIVE NUCLEATION SIZE DISTRIBUTION VINYL-ACETATE STYRENE KINETICS |
| ISSN号 | 0303-402x |
| 通讯作者 | zhang my |
| 中文摘要 | seeded emulsion polymerization and agglomerating method were well-known techniques for the production of polymeric latexes with large particle size and high solid content. obtaining latexes with monodisperse and particle size above 300 nm scale, however, was time-consuming and difficult by means of these methods. here, stable, monodisperse latexes with the controlled particle diameter (55-650 nm) and high solid content (60 wt%) were synthesized via one-step in batch emulsion polymerization. experimental investigations show that the particle size increased with decreasing emulsifier concentrations and increasing monomer/water ratios or electrolyte concentrations. the latex particle coagulation was considered as the dominant particle formation and growth method, which could be proved by the evolutions of particle number as well as dimension against conversion. latex particle coagulation occurred if the particle surface covered ratio dropped between the critical surface covered ratio (theta (crit) = 0.59) and the lowermost surface covered ratio (theta (low) = 0.38). in addition,theta (crit) and theta (low) were increased with electrolyte concentrations. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000324559200013 |
| 公开日期 | 2014-04-15 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/49580]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Liu BJ,Zhang MY,Zhou C,et al. Synthesis of monodisperse, large scale and high solid content latexes of poly(n-butyl acrylate) by a one-step batch emulsion polymerization[J]. colloid and polymer science,2013,291(10):2385-2398. |
| APA | Liu BJ.,Zhang MY.,Zhou C.,Ren L.,Cheng HL.,...&Zhang HX.(2013).Synthesis of monodisperse, large scale and high solid content latexes of poly(n-butyl acrylate) by a one-step batch emulsion polymerization.colloid and polymer science,291(10),2385-2398. |
| MLA | Liu BJ,et al."Synthesis of monodisperse, large scale and high solid content latexes of poly(n-butyl acrylate) by a one-step batch emulsion polymerization".colloid and polymer science 291.10(2013):2385-2398. |
入库方式： OAI收割
来源：长春应用化学研究所
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