Tunable Blue-Green-Emitting Ba3LaNa(PO4)(3)F:Eu2+,Tb3+ Phosphor with Energy Transfer for Near-UV White LEDs
文献类型：期刊论文
| 作者 | Jiao MM ; Guo N ; Lu W ; Jia YC ; Lv WZ ; Zhao Q ; Shao BQ ; You HP |
| 刊名 | inorganic chemistry
 |
| 出版日期 | 2013 |
| 卷号 | 52期号:18页码:10340-10346 |
| 关键词 | OXYFLUORIDE PHOSPHOR LUMINESCENCE DIODES TB3+ PHOTOLUMINESCENCE EXCITATION MECHANISM SYSTEM CE3+ |
| ISSN号 | 1520-510x |
| 通讯作者 | you hp |
| 中文摘要 | a series of eu2+ and eu2+/tb3+ activated novel ba3lana(po4)(3)f phosphors have been synthesized by traditional solid state reaction. rietveld structure refinement of the obtained phosphor indicates that the ba3lana(po4)(3)f host contains three kinds of ba sites. the photoluminescence properties exhibit that the obtained phosphors can be efficiently excited in the range from 320 to 430 nm, which matches perfectly with the commercial n-uv led chips. the critical distance of the eu2+ ions in ba3lana(po4)(3)f:eu2+ is calculated and the energy quenching mechanism is proven to be dipole dipole interaction. tunable blue-green emitting ba3lana (po4)(3)f:eu2+,tb3+ phosphor has been obtained by co-doping eu2+ and tb3+ ions into the host and varying their relative ratios. compared with the tb3+ singly doped phosphor, the codoped phosphors have more intense absorption in the n-uv range and stronger emission of the tb3+ ions, which are attributed to the effective energy transfer from the eu2+ to tb3+ ions. the energy transfer from the eu2+ to tb3+ ions is demonstrated to be a dipole-quadrupole mechanism by the inokuti-hirayama (i-h) model. the eu2+ and tb3+ activated phosphor may be good candidates for blue-green components in n-uv white leds. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000330098300019 |
| 公开日期 | 2014-04-15 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/49611]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Jiao MM,Guo N,Lu W,et al. Tunable Blue-Green-Emitting Ba3LaNa(PO4)(3)F:Eu2+,Tb3+ Phosphor with Energy Transfer for Near-UV White LEDs[J]. inorganic chemistry,2013,52(18):10340-10346. |
| APA | Jiao MM.,Guo N.,Lu W.,Jia YC.,Lv WZ.,...&You HP.(2013).Tunable Blue-Green-Emitting Ba3LaNa(PO4)(3)F:Eu2+,Tb3+ Phosphor with Energy Transfer for Near-UV White LEDs.inorganic chemistry,52(18),10340-10346. |
| MLA | Jiao MM,et al."Tunable Blue-Green-Emitting Ba3LaNa(PO4)(3)F:Eu2+,Tb3+ Phosphor with Energy Transfer for Near-UV White LEDs".inorganic chemistry 52.18(2013):10340-10346. |
入库方式： OAI收割
来源：长春应用化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。