Mechanical, aging, optical and rheological properties of toughening polylactide by melt blending with poly(ethylene glycol) based copolymers
文献类型：期刊论文
| 作者 | Feng LD ; Bian XC ; Chen ZM ; Li G ; Chen XS |
| 刊名 | polymer degradation and stability
 |
| 出版日期 | 2013 |
| 卷号 | 98期号:9页码:1591-1600 |
| 关键词 | BIODEGRADABLE POLYMER BLENDS REACTIVE PROCESSING AGENT POLY(LACTIC ACID) LACTIC-ACID POLY(L-LACTIC ACID) POLY(BUTYLENE ADIPATE-CO-TEREPHTHALATE) ACID)/POLY(EPSILON-CAPROLACTONE) BLENDS CRYSTALLIZATION BEHAVIOR THERMAL-PROPERTIES PHASE MORPHOLOGY |
| ISSN号 | 0141-3910 |
| 通讯作者 | chen xs |
| 中文摘要 | two novel biodegradable copolymers, including poly(ethylene glycol)-succinate copolymer (pes) and poly(ethylene glycol)-succinate-l-lactide copolymer (pesl), have been successfully synthesized via melt polycondensation using sncl2 as a catalyst. the copolymers were used to toughen pla by melt blending. the dsc and sem results indicated that the two copolymers were compatible well with pla, and the compatibility of pesl was superior to that of pes. the results of tensile testing showed that the extensibility of pla was largely improved by blending with pes or pesl. at same blending ratios, the elongation at break of pla/pesl blends was far higher than that of pla/pes ones. the elongation maintained stable through aging for 3 months. the moisture absorption of the blends enhanced due to the strong moisture absorption of peg segments in pes or pesl molecules, which did not directly lead to enhance the hydrolytic degradation rate of the pla. the pla blends containing 20-30 wt% pes or pesl were high transparent materials with high light scattering. the toughening pla materials could potentially be used as a soft biodegradable packaging material or a special optical material. (c) 2013 elsevier ltd. all rights reserved. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000323464200007 |
| 公开日期 | 2014-04-15 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/49650]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Feng LD,Bian XC,Chen ZM,et al. Mechanical, aging, optical and rheological properties of toughening polylactide by melt blending with poly(ethylene glycol) based copolymers[J]. polymer degradation and stability,2013,98(9):1591-1600. |
| APA | Feng LD,Bian XC,Chen ZM,Li G,&Chen XS.(2013).Mechanical, aging, optical and rheological properties of toughening polylactide by melt blending with poly(ethylene glycol) based copolymers.polymer degradation and stability,98(9),1591-1600. |
| MLA | Feng LD,et al."Mechanical, aging, optical and rheological properties of toughening polylactide by melt blending with poly(ethylene glycol) based copolymers".polymer degradation and stability 98.9(2013):1591-1600. |
入库方式： OAI收割
来源：长春应用化学研究所
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