Size Selective Incorporation of Gold Nanoparticles in Diblock Copolymer Vesicle Wall
文献类型：期刊论文
| 作者 | Xu JP ; Han YY ; Cui J ; Jiang W |
| 刊名 | langmuir
 |
| 出版日期 | 2013 |
| 卷号 | 29期号:33页码:10383-10392 |
| 关键词 | BLOCK-COPOLYMER DILUTE-SOLUTION QUANTUM DOTS MICELLES NANOCRYSTALS LOCATION MIXTURES NANOCOMPOSITE SURFACTANTS COMPOSITES |
| ISSN号 | 0743-7463 |
| 通讯作者 | jiang w |
| 中文摘要 | a systematic study is conducted to reveal how far the polymeric vesicle wall can embed gold nanopartides (aunps) with different sizes by combining experiments and self-consistent field simulations. both the experimental and simulative results indicate that the location of aunps in vesicle wall or in spherical micelle is heavily size dependent. whether the aunps enter the vesicle wall or not is determined by a ratio of the diameter of aunps (d-0) to the thickness of the vesicle wall (d(w0)). the 1-dodecanethiol-coated aunps (auxr) with d-0/d(w0) < 0.3 will stably disperse in the vesicle walls. for polystyrene-coated aunps (auxs), a criterion of d-0/d(w0) is proposed based on the phase diagram; i.e., the auxs with d-0/d(w0) < 0.5 can be located in the vesicle wall. otherwise, the auxr and the auxs prefer to locate in spherical micelles. moreover, the contributions of enthalpy and entropy to the total free energy of the system are respectively calculated to reveal the mechanism of the size selective distribution of aunps. the results demonstrate that the escape of aunps from vesicle walls and their selective distribution in spherical micelles is an entropy-driven process. our study provides an important guideline for fabricating nanoparticle/block copolymer hybrid vesicles in dilute solution. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000323472000011 |
| 公开日期 | 2014-04-15 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/49667]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Xu JP,Han YY,Cui J,et al. Size Selective Incorporation of Gold Nanoparticles in Diblock Copolymer Vesicle Wall[J]. langmuir,2013,29(33):10383-10392. |
| APA | Xu JP,Han YY,Cui J,&Jiang W.(2013).Size Selective Incorporation of Gold Nanoparticles in Diblock Copolymer Vesicle Wall.langmuir,29(33),10383-10392. |
| MLA | Xu JP,et al."Size Selective Incorporation of Gold Nanoparticles in Diblock Copolymer Vesicle Wall".langmuir 29.33(2013):10383-10392. |
入库方式： OAI收割
来源：长春应用化学研究所
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