Synthesis of novel polyfluorene with defined group in the center using aryl dipalladium complex as an initiator
文献类型:期刊论文
作者 | Fu HW ; Li J ; Zhang ZL ; Zhan HM ; Li X ; Cheng YX |
刊名 | journal of organometallic chemistry
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出版日期 | 2013 |
卷号 | 738页码:55-58 |
关键词 | CATALYST-TRANSFER POLYCONDENSATION CHAIN-GROWTH POLYCONDENSATION CROSS-COUPLING REACTIONS FIELD-EFFECT TRANSISTORS OXIDATIVE ADDITION CONJUGATED POLYMERS SELF-ORGANIZATION POLYMERIZATION POLY(3-HEXYLTHIOPHENE) MECHANISM |
ISSN号 | 0022-328x |
通讯作者 | zhan hm |
中文摘要 | dinuclear pd(ii) complex dipd-dpe with a bridging ligand c6h4oc6h4-4,4' was successfully synthesized by double oxidative addition reaction of pd(pcy3)(4) with 4,4'-dibromodiphenyl ether in good yield. x-ray crystal structure analysis reveals that the pd atoms have the nearly square-planar coordination geometry with the similar bond lengths of two pd-br as well as four pd-p, implying that two pd(ii) centers have similar reactivity. using the dinuclear pd(ii) complex dipd-dpe as an initiator, novel polyfluorene (pf) with a defined group (c6h4oc6h4-4,4') in the middle of polymer main chain was prepared, demonstrated by maldi-tof analysis. (c) 2013 elsevier b. v. all rights reserved. |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
WOS记录号 | WOS:000319458900009 |
公开日期 | 2014-04-15 |
源URL | [http://ir.ciac.jl.cn/handle/322003/49676] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Fu HW,Li J,Zhang ZL,et al. Synthesis of novel polyfluorene with defined group in the center using aryl dipalladium complex as an initiator[J]. journal of organometallic chemistry,2013,738:55-58. |
APA | Fu HW,Li J,Zhang ZL,Zhan HM,Li X,&Cheng YX.(2013).Synthesis of novel polyfluorene with defined group in the center using aryl dipalladium complex as an initiator.journal of organometallic chemistry,738,55-58. |
MLA | Fu HW,et al."Synthesis of novel polyfluorene with defined group in the center using aryl dipalladium complex as an initiator".journal of organometallic chemistry 738(2013):55-58. |
入库方式: OAI收割
来源:长春应用化学研究所
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