Fluorine-Doped Carbon Blacks: Highly Efficient Metal-Free Electrocatalysts for Oxygen Reduction Reaction
文献类型：期刊论文
| 作者 | Sun XJ ; Zhang YW ; Song P ; Pan J ; Zhuang L ; Xu WL ; Xing W |
| 刊名 | acs catalysis
 |
| 出版日期 | 2013 |
| 卷号 | 3期号:8页码:1726-1729 |
| 关键词 | GRAPHENE QUANTUM DOTS NITROGEN NANOPARTICLES NANOTUBES CATALYST BORON OXIDATION ARRAYS |
| ISSN号 | 2155-5435 |
| 通讯作者 | xu wl |
| 中文摘要 | for the goal of practical industrial development of fuel cells, inexpensive, sustainable, and high performance electrocatalysts for oxygen reduction reactions (orr) are highly desirable alternatives to platinum (pt) and other rare materials. in this work, sustainable fluorine (f)-doped carbon blacks (cb-f) as metal-free, low-cost, and high-performance electrocatalysts for orr were synthesized for the first time. the performance (electrocatalytic activity, long-term operation stability, and tolerance to poisons) of the best one (bp-18f, based on black pearls 2000 (bp)) is on the same level as pt-based or other best non-pt-based catalysts in alkaline medium. the maximum power density of alkaline direct methanol fuel cell with bp-18f as the cathode (3 mg/cm(2)) is similar to 14.56 mw/cm(2) at 60 degrees c, compared with a maximum of 9.44 mw/cm(2) for commercial pt/c (3 mg(pt)/cm(2)). all these results unambiguously demonstrate that these sustainable cb-f catalysts are the most promising alternatives to pt in an alkaline fuel cell. since sustainable carbon blacks are 10 000 times less expensive and much more abundant than pt or other rare materials, these cb-f electrocatalysts possess the best price/performance ratio for orr to date. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000322852900006 |
| 公开日期 | 2014-04-15 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/49697]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Sun XJ,Zhang YW,Song P,et al. Fluorine-Doped Carbon Blacks: Highly Efficient Metal-Free Electrocatalysts for Oxygen Reduction Reaction[J]. acs catalysis,2013,3(8):1726-1729. |
| APA | Sun XJ.,Zhang YW.,Song P.,Pan J.,Zhuang L.,...&Xing W.(2013).Fluorine-Doped Carbon Blacks: Highly Efficient Metal-Free Electrocatalysts for Oxygen Reduction Reaction.acs catalysis,3(8),1726-1729. |
| MLA | Sun XJ,et al."Fluorine-Doped Carbon Blacks: Highly Efficient Metal-Free Electrocatalysts for Oxygen Reduction Reaction".acs catalysis 3.8(2013):1726-1729. |
入库方式： OAI收割
来源：长春应用化学研究所
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