Intrinsic Viscosity of Polymers: General Theory Based on a Partially Permeable Sphere Model
文献类型：期刊论文
| 作者 | Lu YY ; An LJ ; Wang ZG |
| 刊名 | macromolecules
 |
| 出版日期 | 2013 |
| 卷号 | 46期号:14页码:5731-5740 |
| 关键词 | HYPERBRANCHED POLYMERS DILUTE-SOLUTION BIOLOGICAL MACROMOLECULES MOLECULAR-DYNAMICS BROWNIAN DYNAMICS DENDRIMERS POLYSTYRENE BEHAVIOR ARCHITECTURE POLYESTERS |
| ISSN号 | 0024-9297 |
| 通讯作者 | an lj |
| 中文摘要 | we present a general theory for the intrinsic viscosity of flexible polymers of arbitrary architecture. the theory is based on a partially permeable sphere model for which we introduce two phenomenological functions, the drag function xi and the drainage function k, that are determined by the density profile of the polymer. at the mean-field level, these functions capture the long-range, multibody, accumulative hydrodynamic interactions, that are responsible for the frictional dissipation in and around a polymer. the density profiles for a diversity of chain architectures are obtained by monte carlo simulation. predictions from our theory are in good agreement with experimental data on all the polymer structures examined, ranging from linear, ring, and stars to hyperbranched and dendrimers. the concepts and methods we introduce in this work should be useful for studying other dilute solution frictional properties, such as the self-diffusivity, and provide a convenient framework for understanding the relationship between the molecular architecture and their dilute solution properties. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000322417100036 |
| 公开日期 | 2014-04-15 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/49719]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Lu YY,An LJ,Wang ZG. Intrinsic Viscosity of Polymers: General Theory Based on a Partially Permeable Sphere Model[J]. macromolecules,2013,46(14):5731-5740. |
| APA | Lu YY,An LJ,&Wang ZG.(2013).Intrinsic Viscosity of Polymers: General Theory Based on a Partially Permeable Sphere Model.macromolecules,46(14),5731-5740. |
| MLA | Lu YY,et al."Intrinsic Viscosity of Polymers: General Theory Based on a Partially Permeable Sphere Model".macromolecules 46.14(2013):5731-5740. |
入库方式： OAI收割
来源：长春应用化学研究所
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