Novel Functionalized Microporous Organic Networks Based on Triphenylphosphine
文献类型：期刊论文
| 作者 | Zhang Q ; Yang YQ ; Zhang SB |
| 刊名 | chemistry-a european journal
 |
| 出版日期 | 2013 |
| 卷号 | 19期号:30页码:10024-10029 |
| 关键词 | ZEOLITIC IMIDAZOLATE FRAMEWORKS HIGHLY-ACTIVE CATALYSTS CROSS-COUPLING REACTION PALLADIUM NANOPARTICLES CARBON-DIOXIDE SURFACE-AREA HETEROGENEOUS CATALYSIS NANOPOROUS MATERIALS STAUDINGER REACTION CAPTURE PROPERTIES |
| ISSN号 | 0947-6539 |
| 通讯作者 | zhang sb |
| 中文摘要 | this article describes the synthesis and functions of phosphine or phosphine oxide functionalized networks (ppp or pppo; pp=porous polymer). these materials were predominantly microporous and exhibited high surface areas (s-bet: 1284 and 1353m(2)g(-1) for ppp and pppo, respectively), with high co2 (2.46 and 3.83mmolg(-1) for ppp and pppo, respectively) uptake capacities. pd nanoparticles can be simply incorporated into the functionalized networks (ppppd or pppopd) through a facile one-step impregnation. a yield of 98% was obtained in the suzuki reaction between 1-chlorobenzene and p-tolylboronic acid with the ppppd system, which was higher than that obtained when pppopd (53.2%) or [pd(pph3)(4)] (38.2%) was used as the catalyst. the superior catalytic ability of ppppd can be attributed to the structural features that incorporate triarylphosphine within a microporous structure. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000321766400041 |
| 公开日期 | 2014-04-15 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/49721]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Zhang Q,Yang YQ,Zhang SB. Novel Functionalized Microporous Organic Networks Based on Triphenylphosphine[J]. chemistry-a european journal,2013,19(30):10024-10029. |
| APA | Zhang Q,Yang YQ,&Zhang SB.(2013).Novel Functionalized Microporous Organic Networks Based on Triphenylphosphine.chemistry-a european journal,19(30),10024-10029. |
| MLA | Zhang Q,et al."Novel Functionalized Microporous Organic Networks Based on Triphenylphosphine".chemistry-a european journal 19.30(2013):10024-10029. |
入库方式： OAI收割
来源：长春应用化学研究所
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