Electroreductive Transformation of [60]Fullerosultones into Fullerosulfonic Acids
文献类型：期刊论文
| 作者 | Liu R ; Li F ; Xiao Y ; Li DD ; He CL ; Yang WW ; Gao X ; Wang GW |
| 刊名 | journal of organic chemistry
 |
| 出版日期 | 2013 |
| 卷号 | 78期号:14页码:7093-7099 |
| 关键词 | FERRIC PERCHLORATE MEDIATED SYNTHESIS DERIVATIVES C-60 CHEMISTRY FUNCTIONALIZATION FULLERENES ACTIVATION CATALYSTS RADICALS |
| ISSN号 | 0022-3263 |
| 通讯作者 | gao x |
| 中文摘要 | novel c-60 derivatives of a singly bonded dimer and a 1,4-adduct bearing a sulfonic acid functionality have been prepared via the electroreductive transformation of a [60]fullerosultone. it has been shown that the reaction of the in situ formed dianion with benzyl bromide is initiated by a ring-opening of the [60]fullerosultone via the c-60-o bond cleavage upon receiving one electron. the [60]fullerosultone dianion is electrooxidized at 0.40 v to afford the singly bonded dimer species, which can be further electrooxidized at 1.30 v to restore the starting material [60]fullerosultone. the reaction mechanism is studied with the cyclic voltammetry and vis-nir spectroscopy. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000322210700025 |
| 公开日期 | 2014-04-15 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/49724]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Liu R,Li F,Xiao Y,et al. Electroreductive Transformation of [60]Fullerosultones into Fullerosulfonic Acids[J]. journal of organic chemistry,2013,78(14):7093-7099. |
| APA | Liu R.,Li F.,Xiao Y.,Li DD.,He CL.,...&Wang GW.(2013).Electroreductive Transformation of [60]Fullerosultones into Fullerosulfonic Acids.journal of organic chemistry,78(14),7093-7099. |
| MLA | Liu R,et al."Electroreductive Transformation of [60]Fullerosultones into Fullerosulfonic Acids".journal of organic chemistry 78.14(2013):7093-7099. |
入库方式： OAI收割
来源：长春应用化学研究所
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