Copper-Mediated Direct Aryl C-H Cyanation with Azobisisobutyronitrile via a Free-Radical Pathway
文献类型：期刊论文
| 作者 | Xu H ; Liu PT ; Li YH ; Han FS |
| 刊名 | organic letters
 |
| 出版日期 | 2013 |
| 卷号 | 15期号:13页码:3354-3357 |
| 关键词 | PALLADIUM-CATALYZED CYANATION BORONIC ACIDS BONDS CYANIDE N N-DIMETHYLFORMAMIDE |
| ISSN号 | 1523-7060 |
| 通讯作者 | han fs |
| 中文摘要 | an unprecedented protocol for the copper-mediated direct cyanation of aryl c-h by employing 2,2'-azobisisobutyronitrwile (aibn) as a free radical "cn" source is presented. the protocol not only provides a more efficient pathway for the synthesis of aryl nitriles in terms of the yields and the loading amount of copper salts but also, more importantly, represents a novel strategy for aryl c-h cyanation via a cn free-radical mechanism as compared to the cn anion-participating protocols often reported. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000321605800041 |
| 公开日期 | 2014-04-15 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/49746]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Xu H,Liu PT,Li YH,et al. Copper-Mediated Direct Aryl C-H Cyanation with Azobisisobutyronitrile via a Free-Radical Pathway[J]. organic letters,2013,15(13):3354-3357. |
| APA | Xu H,Liu PT,Li YH,&Han FS.(2013).Copper-Mediated Direct Aryl C-H Cyanation with Azobisisobutyronitrile via a Free-Radical Pathway.organic letters,15(13),3354-3357. |
| MLA | Xu H,et al."Copper-Mediated Direct Aryl C-H Cyanation with Azobisisobutyronitrile via a Free-Radical Pathway".organic letters 15.13(2013):3354-3357. |
入库方式： OAI收割
来源：长春应用化学研究所
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