Submicrometer-sized rubber particles as "craze-bridge" for toughening polystyrene/high-impact polystyrene
文献类型：期刊论文
| 作者 | Zhu LD ; Yang HY ; Di Cai G ; Zhou C ; Wu GF ; Zhang MY ; Gao GH ; Zhang HX |
| 刊名 | journal of applied polymer science
 |
| 出版日期 | 2013 |
| 卷号 | 129期号:1页码:224-229 |
| 关键词 | FREE-RADICAL COPOLYMERIZATION SOLUTION POLYMERIZATION GRAFTING REACTIONS METHACRYLATE MONOMERS HIPS POLYBUTADIENE TOUGHNESS MECHANISM DEFORMATION INITIATOR |
| ISSN号 | 0021-8995 |
| 通讯作者 | gao gh |
| 中文摘要 | submicrometer core-shell polybutadiene-graft-polystyrene (pb-g-ps) copolymers were synthesized by emulsion grafting polymerization with 1,2-azobisisobutyronitrile as an initiator. then, pb-g-ps copolymers were blended with high-impact polystyrene (hips) and ps to prepare hips/ps/pb-g-ps. it is generally accepted that ps could only be toughened by 13-m rubber particles effectively. from the izod impact test, however, the results showed that ps could be toughened effectively by submicrometer rubber particles (around 300 nm) in our study. moreover, the impact strength of hips/ps/pb-g-ps is much higher than that of hips due to the synergism between submicrometer rubber particles and micrometer salami particles. subsequently, the stress-whitening zones for hips, ps/pb-g-ps, and hips/ps/pb-g-ps were also observed in detail by transmission electron microscope. based on mechanical properties and deformation morphologies, the deformation mechanism in the hips/ps/pb-g-ps blends was given as follows: crazes could be initiated from large rubber particles, passed through craze-bridge rubber particles, and ended to neighboring small one, which prevented excessively crazing to be form cracks, absorbed energy, and finally enhanced the toughness of ps. (c) 2012 wiley periodicals, inc. j. appl. polym. sci., 2013 |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000317285200025 |
| 公开日期 | 2014-04-15 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/49748]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Zhu LD,Yang HY,Di Cai G,et al. Submicrometer-sized rubber particles as "craze-bridge" for toughening polystyrene/high-impact polystyrene[J]. journal of applied polymer science,2013,129(1):224-229. |
| APA | Zhu LD.,Yang HY.,Di Cai G.,Zhou C.,Wu GF.,...&Zhang HX.(2013).Submicrometer-sized rubber particles as "craze-bridge" for toughening polystyrene/high-impact polystyrene.journal of applied polymer science,129(1),224-229. |
| MLA | Zhu LD,et al."Submicrometer-sized rubber particles as "craze-bridge" for toughening polystyrene/high-impact polystyrene".journal of applied polymer science 129.1(2013):224-229. |
入库方式： OAI收割
来源：长春应用化学研究所
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