A Series of Metal-Organic Frameworks Constructed From a V-shaped Tripodal Carboxylate Ligand: Syntheses, Structures, Photo luminescent, and Magnetic Properties
文献类型：期刊论文
| 作者 | Zhao SN ; Su SQ ; Song XZ ; Zhu M ; Hao ZM ; Meng X ; Song SY ; Zhang HJ |
| 刊名 | crystal growth & design
 |
| 出版日期 | 2013 |
| 卷号 | 13期号:7页码:2756-2765 |
| 关键词 | SECONDARY BUILDING UNITS COORDINATION POLYMERS HYDROTHERMAL SYNTHESIS CRYSTAL-STRUCTURE COMPLEXES DIVERSITY HYDROGEN STORAGE DESIGN SEPARATIONS |
| ISSN号 | 1528-7483 |
| 通讯作者 | zhang hj |
| 中文摘要 | six novel complexes, namely, {[zn-1.5(l)(bix)(1.5)(h2o)].h2o} (1), {[co-1.5(l)(bix)(1.5)(h2o)]h2o}(n) (2), {[co-3(l)(2)(4,4'-bpy)(3)].5h(2)o}(n) (3), {[cd-3(l)(2)(4,4'-bpy)(3)].4.5h(2)o}(n) (4), {[cu-3(l)(2)(4,4'-bpy)3h(2)o}(n) (5), and {[ni-1.5(l)(4,4'-bpy)(1.5)(h2o)(3)].2h(2)o} (6) have been synthesized by the hydrothermal reaction of 5-(4-carboxy-2-nitrophenoxy)isophthalic acid (h3l) with different transition metal ions in the presence of ancillary ligands, 1,4-bis(imidazol-1-ylmethyl)benzene (bix) and 4,4'-bipyridine (4,4'-bpy). complexes 1 and 2 are isostructural, possessing a (3,8)-connected tfz-d type topology with the schlafli symbol of {4(3)}(2){4(6).6(18).8(4)} the 3d structures of complexes 3-5 are very similar to complex 1 with only a little difference of the h3l coordination motif in complexes 4 and 5. meanwhile, we use 4,4'-bpy instead of bix as the ancillary ligand in all three complexes. complex 6 is a mixed one-dimensional chain and two-dimensional sheet structure, which are further linked to each other in a three-dimensional framework by h-bond interactions. all the complexes are characterized by single crystal x-ray diffraction, ir spectroscopy, thermogravimetry analysis, and elemental analysis. in addition, the luminescent properties of complexes 1 and 4 are discussed, and the magnetic properties of complexes 2 and 3 are also investigated. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000321542900010 |
| 公开日期 | 2014-04-15 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/49754]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Zhao SN,Su SQ,Song XZ,et al. A Series of Metal-Organic Frameworks Constructed From a V-shaped Tripodal Carboxylate Ligand: Syntheses, Structures, Photo luminescent, and Magnetic Properties[J]. crystal growth & design,2013,13(7):2756-2765. |
| APA | Zhao SN.,Su SQ.,Song XZ.,Zhu M.,Hao ZM.,...&Zhang HJ.(2013).A Series of Metal-Organic Frameworks Constructed From a V-shaped Tripodal Carboxylate Ligand: Syntheses, Structures, Photo luminescent, and Magnetic Properties.crystal growth & design,13(7),2756-2765. |
| MLA | Zhao SN,et al."A Series of Metal-Organic Frameworks Constructed From a V-shaped Tripodal Carboxylate Ligand: Syntheses, Structures, Photo luminescent, and Magnetic Properties".crystal growth & design 13.7(2013):2756-2765. |
入库方式： OAI收割
来源：长春应用化学研究所
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