Synthesis and characterization of a novel organophosphorus flame retardant and its application in polypropylene
文献类型：期刊论文
| 作者 | Tian NN ; Wen X ; Gong J ; Ma L ; Xue J ; Tang T |
| 刊名 | polymers for advanced technologies
 |
| 出版日期 | 2013 |
| 卷号 | 24期号:7页码:653-659 |
| 关键词 | ACRYLONITRILE-BUTADIENE-STYRENE CAGED BICYCLIC PHOSPHATE AMMONIUM POLYPHOSPHATE THERMAL-DEGRADATION CHARRING AGENT MECHANICAL-PROPERTIES INTUMESCENT PHOSPHORUS SYSTEM ASSOCIATION |
| ISSN号 | 1042-7147 |
| 通讯作者 | tang t |
| 中文摘要 | a novel organophosphorus containing spiro and caged bicyclic phosphate, 3,9-bis-(1-oxo-2,6,7-trioxa-1-phospha-bicyclo[2.2.2]oct-4-ylmethoxy)-2,4,8,10-tetraoxa-3,9-diphospha-spiro[5.5]undecane 3, 9-dioxide (sbcpo), was synthesized and characterized by fourier transform infrared (ftir), hydrogen-1 nuclear magnetic resonance (nmr) and phosphorus-31 nmr. the flame retardancy of polypropylene (pp) containing the novel intumescent flame retardant (ifr) based on the combination between sbcpo and melamine (ma) was studied by limiting oxygen index (loi), ul-94 test and cone calorimeter test. results indicated that this combination showed the excellent flame retardancy for pp at appropriate proportions (with the total loading of 30 wt. % and sbcpo: ma=4:1). the value of loi was as high as 31.6, and the rating in ul94 reached to v-0. moreover, the hrr and thr of ifr/pp decreased significantly in comparison with that of neat pp. the scanning electron microscopy results indicated that the incorporation of sbcpo could induce the formation of intumescent char layer, which retarded the degradation and combustion process of pp. the thermal oxidative degradation of the pp samples at different temperature was analyzed by ftir. the thermal stabilities of the composites were further investigated by thermogravimetric analysis. it was found that the amount of residues was increased greatly with the addition of sbcpo that remained in the form of polyaromatic stacks and phosphoric or polyphosphoric acid at the residual chars. copyright (c) 2013 john wiley & sons, ltd. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000320557400007 |
| 公开日期 | 2014-04-15 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/49764]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Tian NN,Wen X,Gong J,et al. Synthesis and characterization of a novel organophosphorus flame retardant and its application in polypropylene[J]. polymers for advanced technologies,2013,24(7):653-659. |
| APA | Tian NN,Wen X,Gong J,Ma L,Xue J,&Tang T.(2013).Synthesis and characterization of a novel organophosphorus flame retardant and its application in polypropylene.polymers for advanced technologies,24(7),653-659. |
| MLA | Tian NN,et al."Synthesis and characterization of a novel organophosphorus flame retardant and its application in polypropylene".polymers for advanced technologies 24.7(2013):653-659. |
入库方式： OAI收割
来源：长春应用化学研究所
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