Hydrophilic CO2-based biodegradable polycarbonates: Synthesis and rapid thermo-responsive behavior
文献类型：期刊论文
| 作者 | Gu L ; Qin YS ; Gao YG ; Wang XH ; Wang FS |
| 刊名 | journal of polymer science part a-polymer chemistry
 |
| 出版日期 | 2013 |
| 卷号 | 51期号:13页码:2834-2840 |
| 关键词 | CO2/PROPYLENE OXIDE COPOLYMERIZATION CARBON-DIOXIDE PROPYLENE-OXIDE ALTERNATING COPOLYMERIZATION POLY(PROPYLENE CARBONATE) ALUMINUM PORPHYRIN CATALYTIC-SYSTEM MOLECULAR-WEIGHT CO2/EPOXIDE COPOLYMERIZATION STEREOCHEMISTRY CONTROL |
| ISSN号 | 0887-624x |
| 通讯作者 | wang xh |
| 中文摘要 | common co2-based biodegradable polycarbonates like poly(propylene carbonate) or poly(cyclohexene carbonate) are generally hydrophobic, leading to slow biodegradation rate and poor cell adhesion, which limit their applications in the biomedical field. here hydrophilic polycarbonates were prepared by one-pot terpolymerization of co2, propylene oxide (po), and 2-((2-(2-(2-methoxyethoxy)ethoxy)ethoxy)methyl)oxirane (me3mo) using binary salen co(iii)-cl/ppncl catalyst system. the resultant terpolymers showed one glass transition temperature (tg), which decreased with the increase of me3mo units in the terpolymers (fme3mo). water contact angles of the resultant terpolymers with fme3mo of 4.2-23.6% were 68-25 degrees, while that of poly(propylene carbonate) was 90 degrees, indicating that the terpolymers became hydrophlilic. furthermore, the terpolymers with fme3mo more than 25.8% exhibited reversible and rapid thermo-responsive property in water, and the lower critical solution temperature (lcst) was highly sensitive to fme3mo. in particular, aqueous solution of the terpolymer with fme3mo of 72.6% showed a lcst around 35.2 degrees c, close to body temperature, which was promising for biomedical applications, especially for in vivo applications. (c) 2013 wiley periodicals, inc. j. polym. sci., part a: polym. chem. 2013, 51, 2834-2840. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000319681900010 |
| 公开日期 | 2014-04-15 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/49766]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Gu L,Qin YS,Gao YG,et al. Hydrophilic CO2-based biodegradable polycarbonates: Synthesis and rapid thermo-responsive behavior[J]. journal of polymer science part a-polymer chemistry,2013,51(13):2834-2840. |
| APA | Gu L,Qin YS,Gao YG,Wang XH,&Wang FS.(2013).Hydrophilic CO2-based biodegradable polycarbonates: Synthesis and rapid thermo-responsive behavior.journal of polymer science part a-polymer chemistry,51(13),2834-2840. |
| MLA | Gu L,et al."Hydrophilic CO2-based biodegradable polycarbonates: Synthesis and rapid thermo-responsive behavior".journal of polymer science part a-polymer chemistry 51.13(2013):2834-2840. |
入库方式： OAI收割
来源：长春应用化学研究所
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