Synthesis for the Mesomer and Racemate of Thiophene-Based Double Helicene under Irradiation
文献类型：期刊论文
| 作者 | Liu XM ; Yu PP ; Xu L ; Yang JJ ; Shi JW ; Wang ZH ; Cheng YX ; Wang H |
| 刊名 | journal of organic chemistry
 |
| 出版日期 | 2013 |
| 卷号 | 78期号:12页码:6316-6321 |
| 关键词 | CROSS-CONJUGATED OLIGOTHIOPHENES ONE HUNDRED YEARS CARBON-SULFUR ASYMMETRIC-SYNTHESIS CRYSTAL-STRUCTURES STEREOSELECTIVE SYNTHESES BETA-OLIGOTHIOPHENES REMOTE CHIRALITY PHOTOCYCLIZATION CARBOHELICENES |
| ISSN号 | 0022-3263 |
| 通讯作者 | xu l |
| 中文摘要 | in this work, the racernate and mesorner of the thiophene-based naphthalene-cored double helicenes (1) were obtained efficiently by one-pot photocyclization of 1,1,2,2-tetralcis(dithieno[2,3-b:3',2'-d]thiophen-2-yoethene in the presence of iodine in dry benzene. the structure of meso-la was confirmed by single crystal x-ray analysis. the chiral resolution of the racemate was carried out by chiral hplc, and the chiral properties, such as cd spectra, optical rotations, and half-life of enantiorners were characterized. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000320979500052 |
| 公开日期 | 2014-04-15 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/49788]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Liu XM,Yu PP,Xu L,et al. Synthesis for the Mesomer and Racemate of Thiophene-Based Double Helicene under Irradiation[J]. journal of organic chemistry,2013,78(12):6316-6321. |
| APA | Liu XM.,Yu PP.,Xu L.,Yang JJ.,Shi JW.,...&Wang H.(2013).Synthesis for the Mesomer and Racemate of Thiophene-Based Double Helicene under Irradiation.journal of organic chemistry,78(12),6316-6321. |
| MLA | Liu XM,et al."Synthesis for the Mesomer and Racemate of Thiophene-Based Double Helicene under Irradiation".journal of organic chemistry 78.12(2013):6316-6321. |
入库方式： OAI收割
来源：长春应用化学研究所
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