New Insight into a Microfluidic-Based Bipolar System for an Electrochemiluminescence Sensing Platform
文献类型：期刊论文
| 作者 | Zhang XW ; Chen CG ; Li J ; Zhang LB ; Wang EK |
| 刊名 | analytical chemistry
 |
| 出版日期 | 2013 |
| 卷号 | 85期号:11页码:5335-5339 |
| 关键词 | ELECTROGENERATED CHEMILUMINESCENCE REDOX REACTIONS ELECTRODES ELECTROCHEMISTRY ELECTROPHORESIS MICROELECTRODES SENSOR |
| ISSN号 | 0003-2700 |
| 通讯作者 | wang ek |
| 中文摘要 | in this work, a novel style of a microfluidic-based bipolar system with two-direction driving electrodes and dual-channel configuration was described for the first time, which could reach 100% current efficiency in theory. more importantly, the background signal from the integrated driving electrodes was completely eliminated, when this unique design was used to construct an electrochemiluminescence (ecl) sensing platform. first, universal ph indicator was employed to study the mechanism and demonstrate that this new bipolar system possessed 100% current efficiency theoretically. then, the ru(bpy)(3)(2+)/tpra ecl system was introduced to construct the dual-channel bipolar ecl sensing platform, and the results of visual ecl experiments proved that the background signals from the driving electrodes were completely dispelled with our design. to illustrate the promising applications of this dual-channel device, tpra, dopamine (da), h2o2, and k3fe(cn)(6) were detected as model targets under different principles. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000320096900010 |
| 公开日期 | 2014-04-15 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/49806]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Zhang XW,Chen CG,Li J,et al. New Insight into a Microfluidic-Based Bipolar System for an Electrochemiluminescence Sensing Platform[J]. analytical chemistry,2013,85(11):5335-5339. |
| APA | Zhang XW,Chen CG,Li J,Zhang LB,&Wang EK.(2013).New Insight into a Microfluidic-Based Bipolar System for an Electrochemiluminescence Sensing Platform.analytical chemistry,85(11),5335-5339. |
| MLA | Zhang XW,et al."New Insight into a Microfluidic-Based Bipolar System for an Electrochemiluminescence Sensing Platform".analytical chemistry 85.11(2013):5335-5339. |
入库方式： OAI收割
来源：长春应用化学研究所
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